Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes
The interaction of quinolone drugs, ciprofloxacin (CIPH) and norfloxacin (NORH), with zirconyl chloride octahydrate, sodium molybdate dihydrate and sodium tungstate dihydrate was investigated. Elemental analysis, FTIR spectral, electrical conductivity, magnetic susceptibility and UV Visible spectros...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/142646 |
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| author | Khalaf I. Khallow Amaal Y. R. Al-Assaf |
| author_facet | Khalaf I. Khallow Amaal Y. R. Al-Assaf |
| author_sort | Khalaf I. Khallow |
| collection | DOAJ |
| description | The interaction of quinolone drugs, ciprofloxacin (CIPH) and norfloxacin (NORH), with zirconyl chloride octahydrate, sodium molybdate dihydrate and sodium tungstate dihydrate was investigated. Elemental analysis, FTIR spectral, electrical conductivity, magnetic susceptibility and UV Visible spectroscopy measurements have been used to characterize the isolated complexes. The results support the formation of two types of complexes of formula [ZrO(H2O)L2]3H2O and [MO2L2] where L = CIP and NOR; M = Mo and W. FTIR spectra of both types of complexes suggest that CIP and NOR act as deprotonated bidentate ligands through the ring carbonyl oxygen atom and one of the oxygen atom of carboxylic group. |
| format | Article |
| id | doaj-art-2653041aedeb4098ae1b7f9589e847e5 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-2653041aedeb4098ae1b7f9589e847e52025-02-03T05:57:40ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018257658010.1155/2011/142646Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin ComplexesKhalaf I. Khallow0Amaal Y. R. Al-Assaf1Department of Chemistry, College of Education, University of Mosul, IraqDepartment of Chemistry, College of Education, University of Mosul, IraqThe interaction of quinolone drugs, ciprofloxacin (CIPH) and norfloxacin (NORH), with zirconyl chloride octahydrate, sodium molybdate dihydrate and sodium tungstate dihydrate was investigated. Elemental analysis, FTIR spectral, electrical conductivity, magnetic susceptibility and UV Visible spectroscopy measurements have been used to characterize the isolated complexes. The results support the formation of two types of complexes of formula [ZrO(H2O)L2]3H2O and [MO2L2] where L = CIP and NOR; M = Mo and W. FTIR spectra of both types of complexes suggest that CIP and NOR act as deprotonated bidentate ligands through the ring carbonyl oxygen atom and one of the oxygen atom of carboxylic group.http://dx.doi.org/10.1155/2011/142646 |
| spellingShingle | Khalaf I. Khallow Amaal Y. R. Al-Assaf Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes E-Journal of Chemistry |
| title | Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes |
| title_full | Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes |
| title_fullStr | Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes |
| title_full_unstemmed | Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes |
| title_short | Synthesis and Characterization of Oxozirconium(IV), Dioxomolybdenum(VI) and Dioxotungsten(VI) with Ciprofloxacin and Norfloxacin Complexes |
| title_sort | synthesis and characterization of oxozirconium iv dioxomolybdenum vi and dioxotungsten vi with ciprofloxacin and norfloxacin complexes |
| url | http://dx.doi.org/10.1155/2011/142646 |
| work_keys_str_mv | AT khalafikhallow synthesisandcharacterizationofoxozirconiumivdioxomolybdenumvianddioxotungstenviwithciprofloxacinandnorfloxacincomplexes AT amaalyralassaf synthesisandcharacterizationofoxozirconiumivdioxomolybdenumvianddioxotungstenviwithciprofloxacinandnorfloxacincomplexes |