Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon

There has been growing interest in the dyeing of textiles with natural dyes. The research about the adsorption properties of natural dyes can help to understand their adsorption mechanism and to control their dyeing process. This study is concerned with the kinetics and isotherms of adsorption of la...

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Main Authors: Bo Wei, Qiu-Yuan Chen, Guoqiang Chen, Ren-Cheng Tang, Jun Zhang
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/546839
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author Bo Wei
Qiu-Yuan Chen
Guoqiang Chen
Ren-Cheng Tang
Jun Zhang
author_facet Bo Wei
Qiu-Yuan Chen
Guoqiang Chen
Ren-Cheng Tang
Jun Zhang
author_sort Bo Wei
collection DOAJ
description There has been growing interest in the dyeing of textiles with natural dyes. The research about the adsorption properties of natural dyes can help to understand their adsorption mechanism and to control their dyeing process. This study is concerned with the kinetics and isotherms of adsorption of lac dyes on wool, silk, and nylon fibers. It was found that the adsorption kinetics of lac dyes on the three fibers followed the pseudosecond-order kinetic model, and the adsorption rate of lac dyes was the fastest for silk and the slowest for wool. The activation energies for the adsorption process on wool, silk, and nylon were found to be 107.15, 87.85, and 45.31 kJ/mol, respectively. The adsorption of lac dyes on the three fibers followed the Langmuir mechanism, indicating that the electrostatic interactions between lac dyes and those fibers occurred. The saturation values for lac adsorption on the three fibers decreased in the order of wool > silk > nylon; the Langmuir affinity constant of lac adsorption on nylon was much higher than those on wool and silk.
format Article
id doaj-art-26131cab98004a65811749597097ec78
institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-26131cab98004a65811749597097ec782025-02-03T05:57:40ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/546839546839Adsorption Properties of Lac Dyes on Wool, Silk, and NylonBo Wei0Qiu-Yuan Chen1Guoqiang Chen2Ren-Cheng Tang3Jun Zhang4National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, ChinaNational Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, ChinaNational Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, ChinaNational Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, ChinaSuzhou Institute of Trade and Commerce, 287 Xuefu Road, Suzhou 215009, ChinaThere has been growing interest in the dyeing of textiles with natural dyes. The research about the adsorption properties of natural dyes can help to understand their adsorption mechanism and to control their dyeing process. This study is concerned with the kinetics and isotherms of adsorption of lac dyes on wool, silk, and nylon fibers. It was found that the adsorption kinetics of lac dyes on the three fibers followed the pseudosecond-order kinetic model, and the adsorption rate of lac dyes was the fastest for silk and the slowest for wool. The activation energies for the adsorption process on wool, silk, and nylon were found to be 107.15, 87.85, and 45.31 kJ/mol, respectively. The adsorption of lac dyes on the three fibers followed the Langmuir mechanism, indicating that the electrostatic interactions between lac dyes and those fibers occurred. The saturation values for lac adsorption on the three fibers decreased in the order of wool > silk > nylon; the Langmuir affinity constant of lac adsorption on nylon was much higher than those on wool and silk.http://dx.doi.org/10.1155/2013/546839
spellingShingle Bo Wei
Qiu-Yuan Chen
Guoqiang Chen
Ren-Cheng Tang
Jun Zhang
Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
Journal of Chemistry
title Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
title_full Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
title_fullStr Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
title_full_unstemmed Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
title_short Adsorption Properties of Lac Dyes on Wool, Silk, and Nylon
title_sort adsorption properties of lac dyes on wool silk and nylon
url http://dx.doi.org/10.1155/2013/546839
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AT renchengtang adsorptionpropertiesoflacdyesonwoolsilkandnylon
AT junzhang adsorptionpropertiesoflacdyesonwoolsilkandnylon