Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys
In order to measure the very low oxygen potential by use of stabilized zirconia solid electrolyte emf method, a new cell construction was devised. The idea was based on Janke but a zirconia rod was used instead of the zirconia crucible which contacts liquid alloy electrode. The cell was used for...
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University of Belgrade, Technical Faculty, Bor
2012-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200042K.pdf |
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| author | Katayama I. Tanigawa S. Živković D. Hattori Y. Yamashita H. |
| author_facet | Katayama I. Tanigawa S. Živković D. Hattori Y. Yamashita H. |
| author_sort | Katayama I. |
| collection | DOAJ |
| description | In order to measure the very low oxygen potential by use of stabilized zirconia solid electrolyte emf method, a new cell construction was devised. The idea was based on Janke but a zirconia rod was used instead of the zirconia crucible which contacts liquid alloy electrode. The cell was used for determination of the oxygen potentials in liquid dilute Cu-Cr and Cu-Zr alloys. The reference electrode was Cr,Cr2O3. Emf measurements were performed in the temperature range of 1400-1580K and composition range of 0.198-3.10at%Cr-Cu alloys, and 1380-1465K, 0.085-0.761at%Zr-Cu alloys. The composition of liquid alloys were determined by picking up from the liquid alloys and ICP analysis. By use of the newly devised cell construction in this study, stable emf values were obtained at each temperature and alloy composition. Emf values were corrected by using the parameter for electronic contribution of the YSZ. Activity of Cr obeys Henry’s law and activity coefficient at infinitely dilute alloys of Cr in Cu-Cr alloys are: lng0 Cr =(3.80 at 1423K), (3.57 at 1473K), (3.38 at 1523K) and (3.20 at 1573K). At 1423 K activity coefficient of Zr at infinitely diluted alloy is lnγo Zr = -4.0. |
| format | Article |
| id | doaj-art-25f50fec3ecb42a7830409581fdbceee |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-25f50fec3ecb42a7830409581fdbceee2025-02-02T12:47:16ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392012-01-0148333133710.2298/JMMB120827042KNewly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloysKatayama I.Tanigawa S.Živković D.Hattori Y.Yamashita H.In order to measure the very low oxygen potential by use of stabilized zirconia solid electrolyte emf method, a new cell construction was devised. The idea was based on Janke but a zirconia rod was used instead of the zirconia crucible which contacts liquid alloy electrode. The cell was used for determination of the oxygen potentials in liquid dilute Cu-Cr and Cu-Zr alloys. The reference electrode was Cr,Cr2O3. Emf measurements were performed in the temperature range of 1400-1580K and composition range of 0.198-3.10at%Cr-Cu alloys, and 1380-1465K, 0.085-0.761at%Zr-Cu alloys. The composition of liquid alloys were determined by picking up from the liquid alloys and ICP analysis. By use of the newly devised cell construction in this study, stable emf values were obtained at each temperature and alloy composition. Emf values were corrected by using the parameter for electronic contribution of the YSZ. Activity of Cr obeys Henry’s law and activity coefficient at infinitely dilute alloys of Cr in Cu-Cr alloys are: lng0 Cr =(3.80 at 1423K), (3.57 at 1473K), (3.38 at 1523K) and (3.20 at 1573K). At 1423 K activity coefficient of Zr at infinitely diluted alloy is lnγo Zr = -4.0.http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200042K.pdfOxygen sensor developmentZirconia solid electrolyteCu-Cr liquid alloysCu-Zr liquid alloysThermodynamic activity |
| spellingShingle | Katayama I. Tanigawa S. Živković D. Hattori Y. Yamashita H. Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys Journal of Mining and Metallurgy. Section B: Metallurgy Oxygen sensor development Zirconia solid electrolyte Cu-Cr liquid alloys Cu-Zr liquid alloys Thermodynamic activity |
| title | Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys |
| title_full | Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys |
| title_fullStr | Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys |
| title_full_unstemmed | Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys |
| title_short | Newly developed EMF cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid Cu-Cr and Cu-Zr alloys |
| title_sort | newly developed emf cell with zirconia solid electrolyte for measurement of low oxygen potentials in liquid cu cr and cu zr alloys |
| topic | Oxygen sensor development Zirconia solid electrolyte Cu-Cr liquid alloys Cu-Zr liquid alloys Thermodynamic activity |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200042K.pdf |
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