Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands

Binary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-w...

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Main Authors: N. G. Nadkarni, K. V. Mangaonkar
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/924167
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author N. G. Nadkarni
K. V. Mangaonkar
author_facet N. G. Nadkarni
K. V. Mangaonkar
author_sort N. G. Nadkarni
collection DOAJ
description Binary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated.
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institution Kabale University
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publisher Wiley
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spelling doaj-art-25d9e680fa21443cb4d5ecad819cef312025-02-03T01:07:48ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841911191510.1155/2011/924167Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as LigandsN. G. Nadkarni0K. V. Mangaonkar1Patkar College, Goregaon (W), Mumbai - 400062, Maharashtra, IndiaMithibai College, Vile-Parle (W), Mumbai - 400056, Maharashtra, IndiaBinary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated.http://dx.doi.org/10.1155/2011/924167
spellingShingle N. G. Nadkarni
K. V. Mangaonkar
Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
E-Journal of Chemistry
title Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
title_full Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
title_fullStr Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
title_full_unstemmed Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
title_short Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
title_sort stability studies of transition metal chelates of 5 bromosalicylidene 4 methoxyaniline andsalicylidene 2 3 dimethylaniline as ligands
url http://dx.doi.org/10.1155/2011/924167
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AT kvmangaonkar stabilitystudiesoftransitionmetalchelatesof5bromosalicylidene4methoxyanilineandsalicylidene23dimethylanilineasligands