Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands
Binary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-w...
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Language: | English |
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Wiley
2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/924167 |
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author | N. G. Nadkarni K. V. Mangaonkar |
author_facet | N. G. Nadkarni K. V. Mangaonkar |
author_sort | N. G. Nadkarni |
collection | DOAJ |
description | Binary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated. |
format | Article |
id | doaj-art-25d9e680fa21443cb4d5ecad819cef31 |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-25d9e680fa21443cb4d5ecad819cef312025-02-03T01:07:48ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841911191510.1155/2011/924167Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as LigandsN. G. Nadkarni0K. V. Mangaonkar1Patkar College, Goregaon (W), Mumbai - 400062, Maharashtra, IndiaMithibai College, Vile-Parle (W), Mumbai - 400056, Maharashtra, IndiaBinary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5 °C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated.http://dx.doi.org/10.1155/2011/924167 |
spellingShingle | N. G. Nadkarni K. V. Mangaonkar Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands E-Journal of Chemistry |
title | Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands |
title_full | Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands |
title_fullStr | Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands |
title_full_unstemmed | Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands |
title_short | Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands |
title_sort | stability studies of transition metal chelates of 5 bromosalicylidene 4 methoxyaniline andsalicylidene 2 3 dimethylaniline as ligands |
url | http://dx.doi.org/10.1155/2011/924167 |
work_keys_str_mv | AT ngnadkarni stabilitystudiesoftransitionmetalchelatesof5bromosalicylidene4methoxyanilineandsalicylidene23dimethylanilineasligands AT kvmangaonkar stabilitystudiesoftransitionmetalchelatesof5bromosalicylidene4methoxyanilineandsalicylidene23dimethylanilineasligands |