Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups
The electrochemical characteristics of cation-exchange membranes based on polynorbornenes with fluorinated and sulfonated dicarboximide side chain groups were reported. This study was extended to a block copolymer containing structural units with phenyl and 4-oxybenzenesulfonic acid, 2,3,5,6-tetrafl...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2012/835378 |
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| author | Arlette A. Santiago Joel Vargas Mikhail A. Tlenkopatchev Mar López-González Evaristo Riande |
| author_facet | Arlette A. Santiago Joel Vargas Mikhail A. Tlenkopatchev Mar López-González Evaristo Riande |
| author_sort | Arlette A. Santiago |
| collection | DOAJ |
| description | The electrochemical characteristics of cation-exchange membranes based on polynorbornenes with fluorinated and sulfonated dicarboximide side chain groups were reported. This study was extended to a block copolymer containing structural units with phenyl and 4-oxybenzenesulfonic acid, 2,3,5,6-tetrafluorophenyl moieties replacing the hydrogen atom of the dicarboximide group. A thorough study on the electrochemical characteristics of the membranes involving electromotive forces of concentration cells and proton conductivity is reported. The proton permselectivity of the membranes is also discussed. |
| format | Article |
| id | doaj-art-25447680cf1c4250bd724864655c189e |
| institution | Kabale University |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Chemical Engineering |
| spelling | doaj-art-25447680cf1c4250bd724864655c189e2025-02-03T01:28:25ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782012-01-01201210.1155/2012/835378835378Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain GroupsArlette A. Santiago0Joel Vargas1Mikhail A. Tlenkopatchev2Mar López-González3Evaristo Riande4Facultad de Química, Universidad Nacional Autónoma de México, CU, Coyoacán, 04510 México, DF, MexicoFacultad de Ingeniería, Universidad Autónoma del Carmen, Avenida Central S/N Esq. con Fracc. Mundo Maya, 24115 Ciudad del Carmen, CAM, MexicoInstituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, CU, Apartado Postal 70-360, Coyoacán, 04510 México, DF, MexicoInstituto de Ciencia y Tecnología de Polímeros (ICTP-CSIC), C/Juan de la Cierva 3, 28006 Madrid, SpainInstituto de Ciencia y Tecnología de Polímeros (ICTP-CSIC), C/Juan de la Cierva 3, 28006 Madrid, SpainThe electrochemical characteristics of cation-exchange membranes based on polynorbornenes with fluorinated and sulfonated dicarboximide side chain groups were reported. This study was extended to a block copolymer containing structural units with phenyl and 4-oxybenzenesulfonic acid, 2,3,5,6-tetrafluorophenyl moieties replacing the hydrogen atom of the dicarboximide group. A thorough study on the electrochemical characteristics of the membranes involving electromotive forces of concentration cells and proton conductivity is reported. The proton permselectivity of the membranes is also discussed.http://dx.doi.org/10.1155/2012/835378 |
| spellingShingle | Arlette A. Santiago Joel Vargas Mikhail A. Tlenkopatchev Mar López-González Evaristo Riande Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups International Journal of Chemical Engineering |
| title | Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups |
| title_full | Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups |
| title_fullStr | Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups |
| title_full_unstemmed | Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups |
| title_short | Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups |
| title_sort | ion exchange membranes based on polynorbornenes with fluorinated imide side chain groups |
| url | http://dx.doi.org/10.1155/2012/835378 |
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