Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact

A 20 nm Ag coating on Mo back contact was adopted to improve the back contact of evaporated Cu2ZnSnS4 (CZTS) solar cells. The Ag layer helped reduce the thickness of MoS2 which improves fill factor (FF) significantly; additionally, it reduced secondary phases ZnS and SnS2−x, which may help carrier t...

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Main Authors: Hongtao Cui, Chang-Yeh Lee, Wei Li, Xiaolei Liu, Xiaoming Wen, Xiaojing Hao
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2015/170507
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author Hongtao Cui
Chang-Yeh Lee
Wei Li
Xiaolei Liu
Xiaoming Wen
Xiaojing Hao
author_facet Hongtao Cui
Chang-Yeh Lee
Wei Li
Xiaolei Liu
Xiaoming Wen
Xiaojing Hao
author_sort Hongtao Cui
collection DOAJ
description A 20 nm Ag coating on Mo back contact was adopted to improve the back contact of evaporated Cu2ZnSnS4 (CZTS) solar cells. The Ag layer helped reduce the thickness of MoS2 which improves fill factor (FF) significantly; additionally, it reduced secondary phases ZnS and SnS2−x, which may help carrier transport; it was also involved in the doping of the absorber layer, which compensated the intrinsic p-type doping and therefore drags down the doping level. The doping involvement may enlarge the depletion region and improve lifetime of the absorber, which led to enhancing open circuit voltage (VOC), short circuit current density (JSC), and efficiency significantly. However, it degrades the crystallinity of the material slightly.
format Article
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institution Kabale University
issn 1110-662X
1687-529X
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-2500a41d47824c56b2384b88f113c6092025-02-03T06:42:17ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2015-01-01201510.1155/2015/170507170507Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back ContactHongtao Cui0Chang-Yeh Lee1Wei Li2Xiaolei Liu3Xiaoming Wen4Xiaojing Hao5School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, AustraliaA 20 nm Ag coating on Mo back contact was adopted to improve the back contact of evaporated Cu2ZnSnS4 (CZTS) solar cells. The Ag layer helped reduce the thickness of MoS2 which improves fill factor (FF) significantly; additionally, it reduced secondary phases ZnS and SnS2−x, which may help carrier transport; it was also involved in the doping of the absorber layer, which compensated the intrinsic p-type doping and therefore drags down the doping level. The doping involvement may enlarge the depletion region and improve lifetime of the absorber, which led to enhancing open circuit voltage (VOC), short circuit current density (JSC), and efficiency significantly. However, it degrades the crystallinity of the material slightly.http://dx.doi.org/10.1155/2015/170507
spellingShingle Hongtao Cui
Chang-Yeh Lee
Wei Li
Xiaolei Liu
Xiaoming Wen
Xiaojing Hao
Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
International Journal of Photoenergy
title Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
title_full Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
title_fullStr Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
title_full_unstemmed Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
title_short Improving Efficiency of Evaporated Cu2ZnSnS4 Thin Film Solar Cells by a Thin Ag Intermediate Layer between Absorber and Back Contact
title_sort improving efficiency of evaporated cu2znsns4 thin film solar cells by a thin ag intermediate layer between absorber and back contact
url http://dx.doi.org/10.1155/2015/170507
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