Biodiesel Production by Reactive Flash: A Numerical Simulation

Reactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split...

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Main Authors: Alejandro Regalado-Méndez, Sigurd Skogestad, Reyna Natividad, Rubí Romero
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2016/7843081
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author Alejandro Regalado-Méndez
Sigurd Skogestad
Reyna Natividad
Rubí Romero
author_facet Alejandro Regalado-Méndez
Sigurd Skogestad
Reyna Natividad
Rubí Romero
author_sort Alejandro Regalado-Méndez
collection DOAJ
description Reactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ) was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold, (xBiodiesel,T)=(0.46,478.41 K), which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1.
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institution Kabale University
issn 1687-806X
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language English
publishDate 2016-01-01
publisher Wiley
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series International Journal of Chemical Engineering
spelling doaj-art-24cb57de0a394ee0a98740447cd357e92025-02-03T05:52:47ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782016-01-01201610.1155/2016/78430817843081Biodiesel Production by Reactive Flash: A Numerical SimulationAlejandro Regalado-Méndez0Sigurd Skogestad1Reyna Natividad2Rubí Romero3Centro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoDepartment of Chemical Engineering, Norwegian University of Science and Technology (NTNU), 7034 Trondheim, NorwayCentro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoCentro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoReactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ) was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold, (xBiodiesel,T)=(0.46,478.41 K), which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1.http://dx.doi.org/10.1155/2016/7843081
spellingShingle Alejandro Regalado-Méndez
Sigurd Skogestad
Reyna Natividad
Rubí Romero
Biodiesel Production by Reactive Flash: A Numerical Simulation
International Journal of Chemical Engineering
title Biodiesel Production by Reactive Flash: A Numerical Simulation
title_full Biodiesel Production by Reactive Flash: A Numerical Simulation
title_fullStr Biodiesel Production by Reactive Flash: A Numerical Simulation
title_full_unstemmed Biodiesel Production by Reactive Flash: A Numerical Simulation
title_short Biodiesel Production by Reactive Flash: A Numerical Simulation
title_sort biodiesel production by reactive flash a numerical simulation
url http://dx.doi.org/10.1155/2016/7843081
work_keys_str_mv AT alejandroregaladomendez biodieselproductionbyreactiveflashanumericalsimulation
AT sigurdskogestad biodieselproductionbyreactiveflashanumericalsimulation
AT reynanatividad biodieselproductionbyreactiveflashanumericalsimulation
AT rubiromero biodieselproductionbyreactiveflashanumericalsimulation