Biodiesel Production by Reactive Flash: A Numerical Simulation
Reactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split...
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Format: | Article |
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Wiley
2016-01-01
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Series: | International Journal of Chemical Engineering |
Online Access: | http://dx.doi.org/10.1155/2016/7843081 |
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author | Alejandro Regalado-Méndez Sigurd Skogestad Reyna Natividad Rubí Romero |
author_facet | Alejandro Regalado-Méndez Sigurd Skogestad Reyna Natividad Rubí Romero |
author_sort | Alejandro Regalado-Méndez |
collection | DOAJ |
description | Reactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ) was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold, (xBiodiesel,T)=(0.46,478.41 K), which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1. |
format | Article |
id | doaj-art-24cb57de0a394ee0a98740447cd357e9 |
institution | Kabale University |
issn | 1687-806X 1687-8078 |
language | English |
publishDate | 2016-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Chemical Engineering |
spelling | doaj-art-24cb57de0a394ee0a98740447cd357e92025-02-03T05:52:47ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782016-01-01201610.1155/2016/78430817843081Biodiesel Production by Reactive Flash: A Numerical SimulationAlejandro Regalado-Méndez0Sigurd Skogestad1Reyna Natividad2Rubí Romero3Centro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoDepartment of Chemical Engineering, Norwegian University of Science and Technology (NTNU), 7034 Trondheim, NorwayCentro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoCentro Conjunto de Investigación en Química Sustentable UAEMex-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, 50200 Toluca, MEX, MexicoReactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ) was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold, (xBiodiesel,T)=(0.46,478.41 K), which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1.http://dx.doi.org/10.1155/2016/7843081 |
spellingShingle | Alejandro Regalado-Méndez Sigurd Skogestad Reyna Natividad Rubí Romero Biodiesel Production by Reactive Flash: A Numerical Simulation International Journal of Chemical Engineering |
title | Biodiesel Production by Reactive Flash: A Numerical Simulation |
title_full | Biodiesel Production by Reactive Flash: A Numerical Simulation |
title_fullStr | Biodiesel Production by Reactive Flash: A Numerical Simulation |
title_full_unstemmed | Biodiesel Production by Reactive Flash: A Numerical Simulation |
title_short | Biodiesel Production by Reactive Flash: A Numerical Simulation |
title_sort | biodiesel production by reactive flash a numerical simulation |
url | http://dx.doi.org/10.1155/2016/7843081 |
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