Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction

The molten salt electrolysis of LiCl‒KCl is presently the primary method of producing lithium, but it is costly and has environmental issues in addition to other disadvantages. Vacuum thermal reduction may be used extensively in the future because it offers low energy consumption, a high purity prod...

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Main Authors: Di Y.Z., Peng J.P., Wang Y.W., Feng N.X.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2018-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800017D.pdf
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author Di Y.Z.
Peng J.P.
Wang Y.W.
Feng N.X.
author_facet Di Y.Z.
Peng J.P.
Wang Y.W.
Feng N.X.
author_sort Di Y.Z.
collection DOAJ
description The molten salt electrolysis of LiCl‒KCl is presently the primary method of producing lithium, but it is costly and has environmental issues in addition to other disadvantages. Vacuum thermal reduction may be used extensively in the future because it offers low energy consumption, a high purity product and short cycle times. The present study investigated a novel process for the extraction of lithium from Li5AlO4 clinker by vacuum aluminothermic reduction. The Li5AlO4 clinker was prepared in ambient air using lithium hydroxide, alumina and calcium oxide. The results show that this process can proceed in conjunction with a lower ratio of raw materials to lithium (8.89:1) and provides lithium reduction rates in excess of 97%. In addition, the reduction slag consists mainly of 12CaO•7Al2O3, which can be used to produce aluminum hydroxide. Thus, this process represents a highly efficient and environmentally-friendly method of generating lithium.
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institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2018-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-2461a09975f84230830b0c24dece1b9a2025-02-02T20:35:49ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752018-01-0154336937510.2298/JMMB180516017D1450-53391800017DExtracting lithium from a lithium aluminate complex by vacuum aluminothermic reductionDi Y.Z.0Peng J.P.1Wang Y.W.2Feng N.X.3Northeastern University, School of Metallurgy, Shenyang, ChinaNortheastern University, School of Metallurgy, Shenyang, ChinaNortheastern University, School of Metallurgy, Shenyang, ChinaNortheastern University, School of Metallurgy, Shenyang, ChinaThe molten salt electrolysis of LiCl‒KCl is presently the primary method of producing lithium, but it is costly and has environmental issues in addition to other disadvantages. Vacuum thermal reduction may be used extensively in the future because it offers low energy consumption, a high purity product and short cycle times. The present study investigated a novel process for the extraction of lithium from Li5AlO4 clinker by vacuum aluminothermic reduction. The Li5AlO4 clinker was prepared in ambient air using lithium hydroxide, alumina and calcium oxide. The results show that this process can proceed in conjunction with a lower ratio of raw materials to lithium (8.89:1) and provides lithium reduction rates in excess of 97%. In addition, the reduction slag consists mainly of 12CaO•7Al2O3, which can be used to produce aluminum hydroxide. Thus, this process represents a highly efficient and environmentally-friendly method of generating lithium.http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800017D.pdfLithiumVacuumAluminothermic reduction
spellingShingle Di Y.Z.
Peng J.P.
Wang Y.W.
Feng N.X.
Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
Journal of Mining and Metallurgy. Section B: Metallurgy
Lithium
Vacuum
Aluminothermic reduction
title Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
title_full Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
title_fullStr Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
title_full_unstemmed Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
title_short Extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
title_sort extracting lithium from a lithium aluminate complex by vacuum aluminothermic reduction
topic Lithium
Vacuum
Aluminothermic reduction
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800017D.pdf
work_keys_str_mv AT diyz extractinglithiumfromalithiumaluminatecomplexbyvacuumaluminothermicreduction
AT pengjp extractinglithiumfromalithiumaluminatecomplexbyvacuumaluminothermicreduction
AT wangyw extractinglithiumfromalithiumaluminatecomplexbyvacuumaluminothermicreduction
AT fengnx extractinglithiumfromalithiumaluminatecomplexbyvacuumaluminothermicreduction