Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles

Abstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75...

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Main Authors: Abdallah A. Aziz, Hossam F. Nassar, Mona T. Al-Shemy, O. A. Mohamed
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-86798-y
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author Abdallah A. Aziz
Hossam F. Nassar
Mona T. Al-Shemy
O. A. Mohamed
author_facet Abdallah A. Aziz
Hossam F. Nassar
Mona T. Al-Shemy
O. A. Mohamed
author_sort Abdallah A. Aziz
collection DOAJ
description Abstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75, and 1.0% MS-NPs as an additive to WOPC was conducted to analyze the physicomechanical characteristics of WOPC-MS hardened composites, including compressive strength, fire resistance, and water demand. The beneficial impact of biogenic MS-NPS was verified by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and differential thermo-gravimetric analysis (TGA/DTG) methods, revealing several hydration products such as calcium silicate hydrates (CSHs), calcium ferrosilicate hydrates (CFSHs), and calcium aluminosilicate hydrates (CASHs). These products enhance the overall physical and mechanical properties and the thermal stability of hardened WOPC-MS. The composite comprising WOPC-0.75 MS provides numerous advantages from both an economic and environmental perspective.
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series Scientific Reports
spelling doaj-art-243e782c28214c28b8710e4f90b751182025-01-26T12:29:29ZengNature PortfolioScientific Reports2045-23222025-01-0115111710.1038/s41598-025-86798-yBoosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticlesAbdallah A. Aziz0Hossam F. Nassar1Mona T. Al-Shemy2O. A. Mohamed3Environmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityEnvironmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityCellulose and Paper Department, National Research CentreEnvironmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityAbstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75, and 1.0% MS-NPs as an additive to WOPC was conducted to analyze the physicomechanical characteristics of WOPC-MS hardened composites, including compressive strength, fire resistance, and water demand. The beneficial impact of biogenic MS-NPS was verified by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and differential thermo-gravimetric analysis (TGA/DTG) methods, revealing several hydration products such as calcium silicate hydrates (CSHs), calcium ferrosilicate hydrates (CFSHs), and calcium aluminosilicate hydrates (CASHs). These products enhance the overall physical and mechanical properties and the thermal stability of hardened WOPC-MS. The composite comprising WOPC-0.75 MS provides numerous advantages from both an economic and environmental perspective.https://doi.org/10.1038/s41598-025-86798-yCoats-RedfernEco-friendly mesoporous silica nanoparticles (MS-NPs)SustainabilityWhite Ordinary Portland Cement (WOPC)Thermal stability
spellingShingle Abdallah A. Aziz
Hossam F. Nassar
Mona T. Al-Shemy
O. A. Mohamed
Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
Scientific Reports
Coats-Redfern
Eco-friendly mesoporous silica nanoparticles (MS-NPs)
Sustainability
White Ordinary Portland Cement (WOPC)
Thermal stability
title Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
title_full Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
title_fullStr Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
title_full_unstemmed Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
title_short Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
title_sort boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
topic Coats-Redfern
Eco-friendly mesoporous silica nanoparticles (MS-NPs)
Sustainability
White Ordinary Portland Cement (WOPC)
Thermal stability
url https://doi.org/10.1038/s41598-025-86798-y
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