Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles
Abstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75...
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Nature Portfolio
2025-01-01
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Online Access: | https://doi.org/10.1038/s41598-025-86798-y |
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author | Abdallah A. Aziz Hossam F. Nassar Mona T. Al-Shemy O. A. Mohamed |
author_facet | Abdallah A. Aziz Hossam F. Nassar Mona T. Al-Shemy O. A. Mohamed |
author_sort | Abdallah A. Aziz |
collection | DOAJ |
description | Abstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75, and 1.0% MS-NPs as an additive to WOPC was conducted to analyze the physicomechanical characteristics of WOPC-MS hardened composites, including compressive strength, fire resistance, and water demand. The beneficial impact of biogenic MS-NPS was verified by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and differential thermo-gravimetric analysis (TGA/DTG) methods, revealing several hydration products such as calcium silicate hydrates (CSHs), calcium ferrosilicate hydrates (CFSHs), and calcium aluminosilicate hydrates (CASHs). These products enhance the overall physical and mechanical properties and the thermal stability of hardened WOPC-MS. The composite comprising WOPC-0.75 MS provides numerous advantages from both an economic and environmental perspective. |
format | Article |
id | doaj-art-243e782c28214c28b8710e4f90b75118 |
institution | Kabale University |
issn | 2045-2322 |
language | English |
publishDate | 2025-01-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Scientific Reports |
spelling | doaj-art-243e782c28214c28b8710e4f90b751182025-01-26T12:29:29ZengNature PortfolioScientific Reports2045-23222025-01-0115111710.1038/s41598-025-86798-yBoosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticlesAbdallah A. Aziz0Hossam F. Nassar1Mona T. Al-Shemy2O. A. Mohamed3Environmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityEnvironmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityCellulose and Paper Department, National Research CentreEnvironmental Science and Industrial Development Department, Faculty of Postgraduate Studies for Advanced Sciences, Beni-Suef UniversityAbstract This study investigates how biogenic mesoporous silica nanoparticles (MS-NPs) extracted from rice straw residues, a sustainable and economical bio-source, affect White Ordinary Portland Cement (WOPC) paste performance. A comprehensive investigation using varied fractions of 0.25, 0.50, 0.75, and 1.0% MS-NPs as an additive to WOPC was conducted to analyze the physicomechanical characteristics of WOPC-MS hardened composites, including compressive strength, fire resistance, and water demand. The beneficial impact of biogenic MS-NPS was verified by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and differential thermo-gravimetric analysis (TGA/DTG) methods, revealing several hydration products such as calcium silicate hydrates (CSHs), calcium ferrosilicate hydrates (CFSHs), and calcium aluminosilicate hydrates (CASHs). These products enhance the overall physical and mechanical properties and the thermal stability of hardened WOPC-MS. The composite comprising WOPC-0.75 MS provides numerous advantages from both an economic and environmental perspective.https://doi.org/10.1038/s41598-025-86798-yCoats-RedfernEco-friendly mesoporous silica nanoparticles (MS-NPs)SustainabilityWhite Ordinary Portland Cement (WOPC)Thermal stability |
spellingShingle | Abdallah A. Aziz Hossam F. Nassar Mona T. Al-Shemy O. A. Mohamed Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles Scientific Reports Coats-Redfern Eco-friendly mesoporous silica nanoparticles (MS-NPs) Sustainability White Ordinary Portland Cement (WOPC) Thermal stability |
title | Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
title_full | Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
title_fullStr | Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
title_full_unstemmed | Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
title_short | Boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
title_sort | boosting the mechanical performance and fire resistivity of white ordinary portland cement pastes via biogenic mesoporous silica nanoparticles |
topic | Coats-Redfern Eco-friendly mesoporous silica nanoparticles (MS-NPs) Sustainability White Ordinary Portland Cement (WOPC) Thermal stability |
url | https://doi.org/10.1038/s41598-025-86798-y |
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