Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate

A novel semiorganic nonlinear optical crystal bis (L-glutamine) potassium nitrate (BGPN) grown by slow evaporation technique at ambient temperature. The grown crystal surface has been analyzed by chemical etching and atomic force microscopy (AFM) studies. Amplitude parameters like area roughness, ro...

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Main Authors: Redrothu Hanumantharao, S. Kalainathan
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/305932
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author Redrothu Hanumantharao
S. Kalainathan
author_facet Redrothu Hanumantharao
S. Kalainathan
author_sort Redrothu Hanumantharao
collection DOAJ
description A novel semiorganic nonlinear optical crystal bis (L-glutamine) potassium nitrate (BGPN) grown by slow evaporation technique at ambient temperature. The grown crystal surface has been analyzed by chemical etching and atomic force microscopy (AFM) studies. Amplitude parameters like area roughness, roughness average, valley height, valley depth, peak height, and peak valley height were measured successfully from AFM studies. Etching studies were carried out by various solvents like water, methanol and ethanol. The etching study indicates the occurrence of different types of etch pit patterns like striations and steplike pattern. The laser damage threshold energy has been measured by irradiating laser beam using a Q-switched Nd: YAG laser (1064 nm). Second harmonic generation (SHG) studies have been performed by famous Kurtz powder technique with reference to standard potassium dihydrogen phosphate single crystals (KDP). It is found from this technique that SHG efficiency of BGPN is in comparison to that of standard KDP crystals.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2013-01-01
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record_format Article
series Journal of Chemistry
spelling doaj-art-23b8d9a0e3f34e658bb9d87eb72a53c12025-02-03T05:45:27ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/305932305932Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium NitrateRedrothu Hanumantharao0S. Kalainathan1Crystal Research Center, VIT University, Tamilnadu, Vellore 632 014, IndiaCrystal Research Center, VIT University, Tamilnadu, Vellore 632 014, IndiaA novel semiorganic nonlinear optical crystal bis (L-glutamine) potassium nitrate (BGPN) grown by slow evaporation technique at ambient temperature. The grown crystal surface has been analyzed by chemical etching and atomic force microscopy (AFM) studies. Amplitude parameters like area roughness, roughness average, valley height, valley depth, peak height, and peak valley height were measured successfully from AFM studies. Etching studies were carried out by various solvents like water, methanol and ethanol. The etching study indicates the occurrence of different types of etch pit patterns like striations and steplike pattern. The laser damage threshold energy has been measured by irradiating laser beam using a Q-switched Nd: YAG laser (1064 nm). Second harmonic generation (SHG) studies have been performed by famous Kurtz powder technique with reference to standard potassium dihydrogen phosphate single crystals (KDP). It is found from this technique that SHG efficiency of BGPN is in comparison to that of standard KDP crystals.http://dx.doi.org/10.1155/2013/305932
spellingShingle Redrothu Hanumantharao
S. Kalainathan
Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
Journal of Chemistry
title Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
title_full Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
title_fullStr Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
title_full_unstemmed Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
title_short Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine) Potassium Nitrate
title_sort chemical etching afm laser damage threshold and nonlinear optical studies of potential nonlinear optical crystal bis l glutamine potassium nitrate
url http://dx.doi.org/10.1155/2013/305932
work_keys_str_mv AT redrothuhanumantharao chemicaletchingafmlaserdamagethresholdandnonlinearopticalstudiesofpotentialnonlinearopticalcrystalbislglutaminepotassiumnitrate
AT skalainathan chemicaletchingafmlaserdamagethresholdandnonlinearopticalstudiesofpotentialnonlinearopticalcrystalbislglutaminepotassiumnitrate