The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system
The aim of this study was to determine the influence of selected co-adsorbates on the adsorption process of herbicides on activated carbons. 4-Chlorophenoxyacetic acid (4-CPA) and 3-chlorophenoxypropionic acid (3-CPP) were tested as herbicidal active substances. The accompanying substances included...
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Elsevier
2025-01-01
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Series: | Desalination and Water Treatment |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S1944398625000426 |
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author | Magdalena Blachnio Malgorzata Zienkiewicz-Strzalka Anna Derylo-Marczewska |
author_facet | Magdalena Blachnio Malgorzata Zienkiewicz-Strzalka Anna Derylo-Marczewska |
author_sort | Magdalena Blachnio |
collection | DOAJ |
description | The aim of this study was to determine the influence of selected co-adsorbates on the adsorption process of herbicides on activated carbons. 4-Chlorophenoxyacetic acid (4-CPA) and 3-chlorophenoxypropionic acid (3-CPP) were tested as herbicidal active substances. The accompanying substances included 2-nitrophenol (2-NP), 4-nitrophenol (4-NP), 4-nitroaniline (4-NA) and crystal violet (CV). Activated carbon materials were fully characterized by nitrogen adsorption/desorption isotherms, potentiometric titration, X-ray photoelectron spectroscopy, and transmission electron microscopy. Adsorption processes from aqueous solutions were investigated using the static method. The Generalized Langmuir equation (GL) was applied to analyze the adsorption isotherms. Kinetic measurements were also carried out to better understand the mutual influence of herbicides with co-adsorbates. The influence of the properties of co-adsorbates and adsorbents on the efficiency of herbicide removal from the water phase was discussed. |
format | Article |
id | doaj-art-21decd9478e242519f4110204e82a935 |
institution | Kabale University |
issn | 1944-3986 |
language | English |
publishDate | 2025-01-01 |
publisher | Elsevier |
record_format | Article |
series | Desalination and Water Treatment |
spelling | doaj-art-21decd9478e242519f4110204e82a9352025-02-02T05:27:03ZengElsevierDesalination and Water Treatment1944-39862025-01-01321101026The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component systemMagdalena Blachnio0Malgorzata Zienkiewicz-Strzalka1Anna Derylo-Marczewska2Corresponding author.; Department of Physical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, Lublin 20-031, PolandDepartment of Physical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, Lublin 20-031, PolandDepartment of Physical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, Lublin 20-031, PolandThe aim of this study was to determine the influence of selected co-adsorbates on the adsorption process of herbicides on activated carbons. 4-Chlorophenoxyacetic acid (4-CPA) and 3-chlorophenoxypropionic acid (3-CPP) were tested as herbicidal active substances. The accompanying substances included 2-nitrophenol (2-NP), 4-nitrophenol (4-NP), 4-nitroaniline (4-NA) and crystal violet (CV). Activated carbon materials were fully characterized by nitrogen adsorption/desorption isotherms, potentiometric titration, X-ray photoelectron spectroscopy, and transmission electron microscopy. Adsorption processes from aqueous solutions were investigated using the static method. The Generalized Langmuir equation (GL) was applied to analyze the adsorption isotherms. Kinetic measurements were also carried out to better understand the mutual influence of herbicides with co-adsorbates. The influence of the properties of co-adsorbates and adsorbents on the efficiency of herbicide removal from the water phase was discussed.http://www.sciencedirect.com/science/article/pii/S1944398625000426Phenoxyacid herbicideAdsorptionKineticsMulti-component systemActivated carbon |
spellingShingle | Magdalena Blachnio Malgorzata Zienkiewicz-Strzalka Anna Derylo-Marczewska The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system Desalination and Water Treatment Phenoxyacid herbicide Adsorption Kinetics Multi-component system Activated carbon |
title | The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system |
title_full | The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system |
title_fullStr | The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system |
title_full_unstemmed | The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system |
title_short | The influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi-component system |
title_sort | influence of an accompanying substance on the adsorption of herbicides on activated carbon in a multi component system |
topic | Phenoxyacid herbicide Adsorption Kinetics Multi-component system Activated carbon |
url | http://www.sciencedirect.com/science/article/pii/S1944398625000426 |
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