Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction
A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed, and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response spli...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.4061/2011/538341 |
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| _version_ | 1832552829376528384 |
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| author | Milivoj Lovrić Šebojka Komorsky-Lovrić |
| author_facet | Milivoj Lovrić Šebojka Komorsky-Lovrić |
| author_sort | Milivoj Lovrić |
| collection | DOAJ |
| description | A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed, and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency. |
| format | Article |
| id | doaj-art-212aa8521af64d30b9dc592f2f4ccf34 |
| institution | Kabale University |
| issn | 2090-3537 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-212aa8521af64d30b9dc592f2f4ccf342025-02-03T05:57:40ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/538341538341Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan DirectionMilivoj Lovrić0Šebojka Komorsky-Lovrić1Department of Marine and Environmental Research, “Ruđer Bošković” Institute, P.O. Box 180, 10002 Zagreb, Hrvatska, CroatiaDepartment of Marine and Environmental Research, “Ruđer Bošković” Institute, P.O. Box 180, 10002 Zagreb, Hrvatska, CroatiaA theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed, and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency.http://dx.doi.org/10.4061/2011/538341 |
| spellingShingle | Milivoj Lovrić Šebojka Komorsky-Lovrić Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction International Journal of Electrochemistry |
| title | Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction |
| title_full | Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction |
| title_fullStr | Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction |
| title_full_unstemmed | Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction |
| title_short | Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction |
| title_sort | theory of square wave voltammetry of two step electrode reaction using an inverse scan direction |
| url | http://dx.doi.org/10.4061/2011/538341 |
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