Über Reaktionen oxygenierter Kobalt (II)-Chelate VIII. Stereochemischer Verlauf der Oxygenierung des Tris(2-aminoäthyl)amin-Kobalt(II)-Ions

Oxygenation of tris(2-aminoethyl)aminecobalt(II) (= Co(tren)2+) in aqueous solution yields a binuclear complex in which, as shown by X-ray diffraction analysis, the tertiary amino groups of the two 4 dentate ligands are both in cis position regarding the peroxo bridge. This stereospecifity can be e...

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Bibliographic Details
Main Authors: Helmut Mäcke, Silvio Fallab
Format: Article
Language:deu
Published: Swiss Chemical Society 1977-01-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9337
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