Structural Foams of Biobased Isosorbide-Containing Copolycarbonate

Isosorbide-containing copolycarbonate (Bio-PC) is a partly biobased alternative to conventional bisphenol A (BPA) based polycarbonate (PC). Conventional PC is widely used in polymer processing technologies including thermoplastic foaming such as foam injection molding. At present, no detailed data i...

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Main Authors: Stefan Zepnik, Daniel Sander, Stephan Kabasci, Christian Hopmann
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2017/4308687
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author Stefan Zepnik
Daniel Sander
Stephan Kabasci
Christian Hopmann
author_facet Stefan Zepnik
Daniel Sander
Stephan Kabasci
Christian Hopmann
author_sort Stefan Zepnik
collection DOAJ
description Isosorbide-containing copolycarbonate (Bio-PC) is a partly biobased alternative to conventional bisphenol A (BPA) based polycarbonate (PC). Conventional PC is widely used in polymer processing technologies including thermoplastic foaming such as foam injection molding. At present, no detailed data is available concerning the foam injection molding behavior and foam properties of Bio-PC. This contribution provides first results on injection-molded foams based on isosorbide-containing PC. The structural foams were produced by using an endothermic chemical blowing agent (CBA) masterbatch and the low pressure foam injection molding method. The influence of weight reduction and blowing agent concentration on general foam properties such as density, morphology, and mechanical properties was studied. The test specimens consist of a foam core in the center and compact symmetrical shell layers on the sides. The thickness of the foam core increases with increasing weight reduction irrespective of the CBA concentration. The specific (mechanical) bending properties are significantly improved and the specific tensile properties can almost be maintained while reducing the density of the injection-molded parts.
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spelling doaj-art-1ea0a21dde2f4dc98f4982626cf48b4a2025-02-03T01:32:02ZengWileyInternational Journal of Polymer Science1687-94221687-94302017-01-01201710.1155/2017/43086874308687Structural Foams of Biobased Isosorbide-Containing CopolycarbonateStefan Zepnik0Daniel Sander1Stephan Kabasci2Christian Hopmann3Fraunhofer Institute for Environmental, Safety and Energy Technology (Fraunhofer UMSICHT), Oberhausen, GermanyInstitute of Plastics Processing (IKV) in Industry and the Skilled Crafts, RWTH Aachen University, Aachen, GermanyFraunhofer Institute for Environmental, Safety and Energy Technology (Fraunhofer UMSICHT), Oberhausen, GermanyInstitute of Plastics Processing (IKV) in Industry and the Skilled Crafts, RWTH Aachen University, Aachen, GermanyIsosorbide-containing copolycarbonate (Bio-PC) is a partly biobased alternative to conventional bisphenol A (BPA) based polycarbonate (PC). Conventional PC is widely used in polymer processing technologies including thermoplastic foaming such as foam injection molding. At present, no detailed data is available concerning the foam injection molding behavior and foam properties of Bio-PC. This contribution provides first results on injection-molded foams based on isosorbide-containing PC. The structural foams were produced by using an endothermic chemical blowing agent (CBA) masterbatch and the low pressure foam injection molding method. The influence of weight reduction and blowing agent concentration on general foam properties such as density, morphology, and mechanical properties was studied. The test specimens consist of a foam core in the center and compact symmetrical shell layers on the sides. The thickness of the foam core increases with increasing weight reduction irrespective of the CBA concentration. The specific (mechanical) bending properties are significantly improved and the specific tensile properties can almost be maintained while reducing the density of the injection-molded parts.http://dx.doi.org/10.1155/2017/4308687
spellingShingle Stefan Zepnik
Daniel Sander
Stephan Kabasci
Christian Hopmann
Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
International Journal of Polymer Science
title Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
title_full Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
title_fullStr Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
title_full_unstemmed Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
title_short Structural Foams of Biobased Isosorbide-Containing Copolycarbonate
title_sort structural foams of biobased isosorbide containing copolycarbonate
url http://dx.doi.org/10.1155/2017/4308687
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AT christianhopmann structuralfoamsofbiobasedisosorbidecontainingcopolycarbonate