A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste

To manage the polycotton textile-waste fabric (PCWF), a modified alkaline hydrolysis method is used for decolorization and separation of polyester as terephthalic acid (TPA). The effects of optimum conditions on TPA yield (%) have been determined to be 97.66±1.94%. Dye degradations and K/S values ar...

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Main Authors: S. S. Nahar, M. S. Rahaman, R. Samadder, F. R. Shagor, R. K. Chadni, Mubarak A. Khan
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Polymer Technology
Online Access:http://dx.doi.org/10.1155/2022/4325506
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author S. S. Nahar
M. S. Rahaman
R. Samadder
F. R. Shagor
R. K. Chadni
M. S. Rahaman
Mubarak A. Khan
author_facet S. S. Nahar
M. S. Rahaman
R. Samadder
F. R. Shagor
R. K. Chadni
M. S. Rahaman
Mubarak A. Khan
author_sort S. S. Nahar
collection DOAJ
description To manage the polycotton textile-waste fabric (PCWF), a modified alkaline hydrolysis method is used for decolorization and separation of polyester as terephthalic acid (TPA). The effects of optimum conditions on TPA yield (%) have been determined to be 97.66±1.94%. Dye degradations and K/S values are measured by UV-visible spectrophotometer. K/S value of PCWF is 37.06 and separated cotton fabric (SCF) is 0.035, respectively. The chemical functionalities and crystallinity of PCWF, SCF, and TPA are determined by using FTIR and XRD. FTIR peak values are 1684 cm-1, 1574 cm-1, 1512 cm-1, 1280 cm-1, and 1425 cm-1 that prove transformation of polyester to TPA. XRD peaks confirm polyester conversion to TPA, and the values are 17.4, 25.13, 28.12, 29.09, and 38.7. TGA, SEM, and EDX data showed the thermal stability, morphology, and elemental composition of TPA.
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institution Kabale University
issn 1098-2329
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publishDate 2022-01-01
publisher Wiley
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series Advances in Polymer Technology
spelling doaj-art-1c0f0adcf37d4836842c95283ac16f862025-02-03T01:00:43ZengWileyAdvances in Polymer Technology1098-23292022-01-01202210.1155/2022/4325506A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid WasteS. S. Nahar0M. S. Rahaman1R. Samadder2F. R. Shagor3R. K. Chadni4M. S. Rahaman5Mubarak A. Khan6Research LabResearch LabDepartment of ChemistryResearch LabResearch LabInstitute of Nuclear Science and TechnologyResearch LabTo manage the polycotton textile-waste fabric (PCWF), a modified alkaline hydrolysis method is used for decolorization and separation of polyester as terephthalic acid (TPA). The effects of optimum conditions on TPA yield (%) have been determined to be 97.66±1.94%. Dye degradations and K/S values are measured by UV-visible spectrophotometer. K/S value of PCWF is 37.06 and separated cotton fabric (SCF) is 0.035, respectively. The chemical functionalities and crystallinity of PCWF, SCF, and TPA are determined by using FTIR and XRD. FTIR peak values are 1684 cm-1, 1574 cm-1, 1512 cm-1, 1280 cm-1, and 1425 cm-1 that prove transformation of polyester to TPA. XRD peaks confirm polyester conversion to TPA, and the values are 17.4, 25.13, 28.12, 29.09, and 38.7. TGA, SEM, and EDX data showed the thermal stability, morphology, and elemental composition of TPA.http://dx.doi.org/10.1155/2022/4325506
spellingShingle S. S. Nahar
M. S. Rahaman
R. Samadder
F. R. Shagor
R. K. Chadni
M. S. Rahaman
Mubarak A. Khan
A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
Advances in Polymer Technology
title A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
title_full A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
title_fullStr A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
title_full_unstemmed A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
title_short A Modified Hydrolysis Method of Decolorizing Reactive-Dyed Polycotton Waste Fabric and Extraction of Terephthalic Acid: A Perspective to Reduce Textile Solid Waste
title_sort modified hydrolysis method of decolorizing reactive dyed polycotton waste fabric and extraction of terephthalic acid a perspective to reduce textile solid waste
url http://dx.doi.org/10.1155/2022/4325506
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