Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead

Valorization of Lantana camara L., which is a recognized invasive plant, as a potential source of activated carbon is proposed in this study. Its stem and leaf have been utilized for the preparation of activated carbon (ACL and ACS) by following acid-impregnation technique, followed by thermal treat...

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Main Authors: Vipin Kumar Saini, Surindra Suthar, Chaudhari Karmveer, Kapil Kumar
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2017/5612594
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author Vipin Kumar Saini
Surindra Suthar
Chaudhari Karmveer
Kapil Kumar
author_facet Vipin Kumar Saini
Surindra Suthar
Chaudhari Karmveer
Kapil Kumar
author_sort Vipin Kumar Saini
collection DOAJ
description Valorization of Lantana camara L., which is a recognized invasive plant, as a potential source of activated carbon is proposed in this study. Its stem and leaf have been utilized for the preparation of activated carbon (ACL and ACS) by following acid-impregnation technique, followed by thermal treatment. The developed activated carbon samples were characterized for their structural and surface related properties by low-temperature nitrogen adsorption isotherm, SEM techniques, and pHPZC method. The samples show reasonable high surface area and pore volume; nonetheless, these properties are higher in case of ACL as compraed to ACS. Both of these samples developed negative charge on their surface due to acid treatment that resulted in an increase in adsorption at pH > 5. The batch adsorption studies on these samples shows the Pb(II) ion adsorption capacities of ACL and ACS were 36.01 and 32.24 mg·g−1, respectively, at 25°C. The kinetics of adsorption with both the sample systems follow the pseudo-second-order model, whereas the experimental equilibrium isotherm data of ACL and ACS were explained by Freundlich and Langmuir models, respectively. For these samples, the HCl shows maximum desorption with which the recycling test on these samples shows that ACS has better recycling potential over ACL samples.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2017-01-01
publisher Wiley
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series Journal of Chemistry
spelling doaj-art-1bf1a6982fbf4cc6ab5e7090be72caf82025-02-03T01:30:49ZengWileyJournal of Chemistry2090-90632090-90712017-01-01201710.1155/2017/56125945612594Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of LeadVipin Kumar Saini0Surindra Suthar1Chaudhari Karmveer2Kapil Kumar3School of Environment & Natural Resources, Doon University, Dehradun, Uttarakhand 248001, IndiaSchool of Environment & Natural Resources, Doon University, Dehradun, Uttarakhand 248001, IndiaSchool of Environment & Natural Resources, Doon University, Dehradun, Uttarakhand 248001, IndiaDepartment of Environmental Engineering, National Institute of Technology, New Delhi 110040, IndiaValorization of Lantana camara L., which is a recognized invasive plant, as a potential source of activated carbon is proposed in this study. Its stem and leaf have been utilized for the preparation of activated carbon (ACL and ACS) by following acid-impregnation technique, followed by thermal treatment. The developed activated carbon samples were characterized for their structural and surface related properties by low-temperature nitrogen adsorption isotherm, SEM techniques, and pHPZC method. The samples show reasonable high surface area and pore volume; nonetheless, these properties are higher in case of ACL as compraed to ACS. Both of these samples developed negative charge on their surface due to acid treatment that resulted in an increase in adsorption at pH > 5. The batch adsorption studies on these samples shows the Pb(II) ion adsorption capacities of ACL and ACS were 36.01 and 32.24 mg·g−1, respectively, at 25°C. The kinetics of adsorption with both the sample systems follow the pseudo-second-order model, whereas the experimental equilibrium isotherm data of ACL and ACS were explained by Freundlich and Langmuir models, respectively. For these samples, the HCl shows maximum desorption with which the recycling test on these samples shows that ACS has better recycling potential over ACL samples.http://dx.doi.org/10.1155/2017/5612594
spellingShingle Vipin Kumar Saini
Surindra Suthar
Chaudhari Karmveer
Kapil Kumar
Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
Journal of Chemistry
title Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
title_full Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
title_fullStr Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
title_full_unstemmed Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
title_short Valorization of Toxic Weed Lantana camara L. Biomass for Adsorptive Removal of Lead
title_sort valorization of toxic weed lantana camara l biomass for adsorptive removal of lead
url http://dx.doi.org/10.1155/2017/5612594
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AT surindrasuthar valorizationoftoxicweedlantanacamaralbiomassforadsorptiveremovaloflead
AT chaudharikarmveer valorizationoftoxicweedlantanacamaralbiomassforadsorptiveremovaloflead
AT kapilkumar valorizationoftoxicweedlantanacamaralbiomassforadsorptiveremovaloflead