Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications

Traditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excelle...

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Main Authors: Muhammad Afiq Irfan Mohd Shumiri, Abdillah Sani Mohd Najib, Andi Erwin Eka Putra, Nor Akmal Fadil
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Science and Technology of Advanced Materials
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Online Access:https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017
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author Muhammad Afiq Irfan Mohd Shumiri
Abdillah Sani Mohd Najib
Andi Erwin Eka Putra
Nor Akmal Fadil
author_facet Muhammad Afiq Irfan Mohd Shumiri
Abdillah Sani Mohd Najib
Andi Erwin Eka Putra
Nor Akmal Fadil
author_sort Muhammad Afiq Irfan Mohd Shumiri
collection DOAJ
description Traditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excellent electron conductivity, efficient mass transport and remarkable catalytic activity, positioning them at the forefront of nanomaterial applications with significant potential. However, reproducible synthesis of these structures remains challenging due to limitations in conventional dealloying techniques. Herein, this review attempts to consolidate recent progress in electrochemical and chemical dealloying methods for nanoporous anodes in energy storage and conversion applications. We begin by elucidating the fundamental mechanisms driving dealloying and evaluate key factors influencing dealloying conditions. Through a review of current research, we identify critical properties of dealloyed nanoporous anodes that warrant further investigation. Applications of these materials as anodes in metal-ion batteries, supercapacitors, water splitting and photocatalyst are discussed. Lastly, we address ongoing challenges in this field and propose perspectives on promising research directions. This review aims to inspire new pathways and foster the development of efficient dealloyed porous anodes for sustainable energy technologies.
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series Science and Technology of Advanced Materials
spelling doaj-art-1b49fa4f38fc4857876e77cea646a81a2025-02-03T10:24:43ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142025-12-0126110.1080/14686996.2025.2451017Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applicationsMuhammad Afiq Irfan Mohd Shumiri0Abdillah Sani Mohd Najib1Andi Erwin Eka Putra2Nor Akmal Fadil3Materials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaMaterials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaBattery and Advanced Materials Research Center, Hasanuddin University, Makassar, IndonesiaMaterials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaTraditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excellent electron conductivity, efficient mass transport and remarkable catalytic activity, positioning them at the forefront of nanomaterial applications with significant potential. However, reproducible synthesis of these structures remains challenging due to limitations in conventional dealloying techniques. Herein, this review attempts to consolidate recent progress in electrochemical and chemical dealloying methods for nanoporous anodes in energy storage and conversion applications. We begin by elucidating the fundamental mechanisms driving dealloying and evaluate key factors influencing dealloying conditions. Through a review of current research, we identify critical properties of dealloyed nanoporous anodes that warrant further investigation. Applications of these materials as anodes in metal-ion batteries, supercapacitors, water splitting and photocatalyst are discussed. Lastly, we address ongoing challenges in this field and propose perspectives on promising research directions. This review aims to inspire new pathways and foster the development of efficient dealloyed porous anodes for sustainable energy technologies.https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017Electrochemical dealloyingenergy storageporous structureanode modificationscycle stabilityfunctionalized materials performance
spellingShingle Muhammad Afiq Irfan Mohd Shumiri
Abdillah Sani Mohd Najib
Andi Erwin Eka Putra
Nor Akmal Fadil
Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
Science and Technology of Advanced Materials
Electrochemical dealloying
energy storage
porous structure
anode modifications
cycle stability
functionalized materials performance
title Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
title_full Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
title_fullStr Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
title_full_unstemmed Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
title_short Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
title_sort electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
topic Electrochemical dealloying
energy storage
porous structure
anode modifications
cycle stability
functionalized materials performance
url https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017
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AT abdillahsanimohdnajib electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications
AT andierwinekaputra electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications
AT norakmalfadil electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications