Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications
Traditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excelle...
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Taylor & Francis Group
2025-12-01
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Series: | Science and Technology of Advanced Materials |
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Online Access: | https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017 |
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author | Muhammad Afiq Irfan Mohd Shumiri Abdillah Sani Mohd Najib Andi Erwin Eka Putra Nor Akmal Fadil |
author_facet | Muhammad Afiq Irfan Mohd Shumiri Abdillah Sani Mohd Najib Andi Erwin Eka Putra Nor Akmal Fadil |
author_sort | Muhammad Afiq Irfan Mohd Shumiri |
collection | DOAJ |
description | Traditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excellent electron conductivity, efficient mass transport and remarkable catalytic activity, positioning them at the forefront of nanomaterial applications with significant potential. However, reproducible synthesis of these structures remains challenging due to limitations in conventional dealloying techniques. Herein, this review attempts to consolidate recent progress in electrochemical and chemical dealloying methods for nanoporous anodes in energy storage and conversion applications. We begin by elucidating the fundamental mechanisms driving dealloying and evaluate key factors influencing dealloying conditions. Through a review of current research, we identify critical properties of dealloyed nanoporous anodes that warrant further investigation. Applications of these materials as anodes in metal-ion batteries, supercapacitors, water splitting and photocatalyst are discussed. Lastly, we address ongoing challenges in this field and propose perspectives on promising research directions. This review aims to inspire new pathways and foster the development of efficient dealloyed porous anodes for sustainable energy technologies. |
format | Article |
id | doaj-art-1b49fa4f38fc4857876e77cea646a81a |
institution | Kabale University |
issn | 1468-6996 1878-5514 |
language | English |
publishDate | 2025-12-01 |
publisher | Taylor & Francis Group |
record_format | Article |
series | Science and Technology of Advanced Materials |
spelling | doaj-art-1b49fa4f38fc4857876e77cea646a81a2025-02-03T10:24:43ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142025-12-0126110.1080/14686996.2025.2451017Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applicationsMuhammad Afiq Irfan Mohd Shumiri0Abdillah Sani Mohd Najib1Andi Erwin Eka Putra2Nor Akmal Fadil3Materials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaMaterials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaBattery and Advanced Materials Research Center, Hasanuddin University, Makassar, IndonesiaMaterials Research and Consultancy Group, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, Johor Bahru, MalaysiaTraditionally employed in alloy corrosion studies, dealloying has evolved into a versatile technique for fabricating advanced porous materials. The unique architecture of interconnected pore channels and continuous metal ligaments endows dealloyed materials with high surface-to-volume ratio, excellent electron conductivity, efficient mass transport and remarkable catalytic activity, positioning them at the forefront of nanomaterial applications with significant potential. However, reproducible synthesis of these structures remains challenging due to limitations in conventional dealloying techniques. Herein, this review attempts to consolidate recent progress in electrochemical and chemical dealloying methods for nanoporous anodes in energy storage and conversion applications. We begin by elucidating the fundamental mechanisms driving dealloying and evaluate key factors influencing dealloying conditions. Through a review of current research, we identify critical properties of dealloyed nanoporous anodes that warrant further investigation. Applications of these materials as anodes in metal-ion batteries, supercapacitors, water splitting and photocatalyst are discussed. Lastly, we address ongoing challenges in this field and propose perspectives on promising research directions. This review aims to inspire new pathways and foster the development of efficient dealloyed porous anodes for sustainable energy technologies.https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017Electrochemical dealloyingenergy storageporous structureanode modificationscycle stabilityfunctionalized materials performance |
spellingShingle | Muhammad Afiq Irfan Mohd Shumiri Abdillah Sani Mohd Najib Andi Erwin Eka Putra Nor Akmal Fadil Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications Science and Technology of Advanced Materials Electrochemical dealloying energy storage porous structure anode modifications cycle stability functionalized materials performance |
title | Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
title_full | Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
title_fullStr | Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
title_full_unstemmed | Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
title_short | Electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
title_sort | electrochemical and chemical dealloying of nanoporous anode materials for energy storage applications |
topic | Electrochemical dealloying energy storage porous structure anode modifications cycle stability functionalized materials performance |
url | https://www.tandfonline.com/doi/10.1080/14686996.2025.2451017 |
work_keys_str_mv | AT muhammadafiqirfanmohdshumiri electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications AT abdillahsanimohdnajib electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications AT andierwinekaputra electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications AT norakmalfadil electrochemicalandchemicaldealloyingofnanoporousanodematerialsforenergystorageapplications |