Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites

Natural rubber (NR) composites filled with silica and crosslinked with phenolic resin were prepared in this study. The influence of a small sepiolite addition (1–5 part(s) per hundred parts of rubber, phr) on the properties of NR composites was studied. It was found that sepiolite reduced silica agg...

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Main Authors: Nabil Hayeemasae, Sitisaiyidah Saiwari, Siriwat Soontaranon, Mohamad Irfan Fathurrohman, Abdulhakim Masa
Format: Article
Language:English
Published: Budapest University of Technology 2025-03-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0013200&mi=cd
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author Nabil Hayeemasae
Sitisaiyidah Saiwari
Siriwat Soontaranon
Mohamad Irfan Fathurrohman
Abdulhakim Masa
author_facet Nabil Hayeemasae
Sitisaiyidah Saiwari
Siriwat Soontaranon
Mohamad Irfan Fathurrohman
Abdulhakim Masa
author_sort Nabil Hayeemasae
collection DOAJ
description Natural rubber (NR) composites filled with silica and crosslinked with phenolic resin were prepared in this study. The influence of a small sepiolite addition (1–5 part(s) per hundred parts of rubber, phr) on the properties of NR composites was studied. It was found that sepiolite reduced silica aggregate size, allowing improved dispersion in the NR matrix. Sepiolite facilitates silica dispersion by locating at the silica surfaces and acting as a barrier that prevents agglomeration of silica filler. The swelling resistance, crosslink density, tensile strength, and strain-induced crystallization were all strengthened by incorporating sepiolite because of the improved silica dispersion. The greatest tensile strength was achieved at a 2 phr sepiolite addition level. The improvement was about 18% over the reference composite due to the greatest filler-rubber interactions and the finest filler dispersion. The results clearly indicate that sepiolite clay can be applied as a dispersing agent in silica-containing rubber composites.
format Article
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institution Kabale University
issn 1788-618X
language English
publishDate 2025-03-01
publisher Budapest University of Technology
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series eXPRESS Polymer Letters
spelling doaj-art-19464f4d38734014abf7f50c687267522025-01-23T14:54:56ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2025-03-0119333934910.3144/expresspolymlett.2025.24Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica compositesNabil HayeemasaeSitisaiyidah SaiwariSiriwat SoontaranonMohamad Irfan FathurrohmanAbdulhakim MasaNatural rubber (NR) composites filled with silica and crosslinked with phenolic resin were prepared in this study. The influence of a small sepiolite addition (1–5 part(s) per hundred parts of rubber, phr) on the properties of NR composites was studied. It was found that sepiolite reduced silica aggregate size, allowing improved dispersion in the NR matrix. Sepiolite facilitates silica dispersion by locating at the silica surfaces and acting as a barrier that prevents agglomeration of silica filler. The swelling resistance, crosslink density, tensile strength, and strain-induced crystallization were all strengthened by incorporating sepiolite because of the improved silica dispersion. The greatest tensile strength was achieved at a 2 phr sepiolite addition level. The improvement was about 18% over the reference composite due to the greatest filler-rubber interactions and the finest filler dispersion. The results clearly indicate that sepiolite clay can be applied as a dispersing agent in silica-containing rubber composites.http://www.expresspolymlett.com/letolt.php?file=EPL-0013200&mi=cd crosslinking elastomer filler natural rubber silica
spellingShingle Nabil Hayeemasae
Sitisaiyidah Saiwari
Siriwat Soontaranon
Mohamad Irfan Fathurrohman
Abdulhakim Masa
Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
eXPRESS Polymer Letters
crosslinking
elastomer
filler
natural rubber
silica
title Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
title_full Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
title_fullStr Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
title_full_unstemmed Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
title_short Potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber/silica composites
title_sort potential for using sepiolite as dispersing agent in phenolic resin crosslinked natural rubber silica composites
topic crosslinking
elastomer
filler
natural rubber
silica
url http://www.expresspolymlett.com/letolt.php?file=EPL-0013200&mi=cd
work_keys_str_mv AT nabilhayeemasae potentialforusingsepioliteasdispersingagentinphenolicresincrosslinkednaturalrubbersilicacomposites
AT sitisaiyidahsaiwari potentialforusingsepioliteasdispersingagentinphenolicresincrosslinkednaturalrubbersilicacomposites
AT siriwatsoontaranon potentialforusingsepioliteasdispersingagentinphenolicresincrosslinkednaturalrubbersilicacomposites
AT mohamadirfanfathurrohman potentialforusingsepioliteasdispersingagentinphenolicresincrosslinkednaturalrubbersilicacomposites
AT abdulhakimmasa potentialforusingsepioliteasdispersingagentinphenolicresincrosslinkednaturalrubbersilicacomposites