Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption

The dye, Grey BL was adsorbed on an adsorbent prepared from mature leaves of the Pungan tree (Pongamia glabra). A batch adsorption study was carried out with variable adsorbate concentration, adsorbent amount and pH. Ninety three percent of the dye could be removed by 2 g of the derris leaf powder f...

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Main Authors: T. Mugugan, A. Ganapathi, R. Valliappan
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/938692
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author T. Mugugan
A. Ganapathi
R. Valliappan
author_facet T. Mugugan
A. Ganapathi
R. Valliappan
author_sort T. Mugugan
collection DOAJ
description The dye, Grey BL was adsorbed on an adsorbent prepared from mature leaves of the Pungan tree (Pongamia glabra). A batch adsorption study was carried out with variable adsorbate concentration, adsorbent amount and pH. Ninety three percent of the dye could be removed by 2 g of the derris leaf powder from 1 L of an aqueous solution containing 25 mg of the dye at 300 K. The adsorption followed pseudo first order kinetics with a mean rate constant of 3.73 ×10-3 min-1 and an intraparticle diffusion rate constant of 6.36 x10-2 mg g-1 min-0.5. A possible mechanism of adsorption was suggested on the basis of concurrently operating surface adsorption and pore diffusion. The experimental data yielded excellent fits with Langmuir and Freundlich isotherm equations. The Langmuir monolayer capacity had a mean value of 8.27 mg g-1. The results indicated that the dye, Grey BL, strongly interacts with a biomass-based adsorbent, the Derris (Pongamia glabra) leaf powder.
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language English
publishDate 2010-01-01
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spelling doaj-art-18fa62b8a2b5454f9613617bc4c715d32025-02-03T01:10:11ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-01741454146210.1155/2010/938692Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by AdsorptionT. Mugugan0A. Ganapathi1R. Valliappan2Division of Chemistry, Faculty of Engineering and Technology, Chemistry Wing, DDE Annamalai University, Annamalai Nagar-608 002, IndiaDivision of Chemistry, Faculty of Engineering and Technology, Chemistry Wing, DDE Annamalai University, Annamalai Nagar-608 002, IndiaDivision of Chemistry, Faculty of Engineering and Technology, Chemistry Wing, DDE Annamalai University, Annamalai Nagar-608 002, IndiaThe dye, Grey BL was adsorbed on an adsorbent prepared from mature leaves of the Pungan tree (Pongamia glabra). A batch adsorption study was carried out with variable adsorbate concentration, adsorbent amount and pH. Ninety three percent of the dye could be removed by 2 g of the derris leaf powder from 1 L of an aqueous solution containing 25 mg of the dye at 300 K. The adsorption followed pseudo first order kinetics with a mean rate constant of 3.73 ×10-3 min-1 and an intraparticle diffusion rate constant of 6.36 x10-2 mg g-1 min-0.5. A possible mechanism of adsorption was suggested on the basis of concurrently operating surface adsorption and pore diffusion. The experimental data yielded excellent fits with Langmuir and Freundlich isotherm equations. The Langmuir monolayer capacity had a mean value of 8.27 mg g-1. The results indicated that the dye, Grey BL, strongly interacts with a biomass-based adsorbent, the Derris (Pongamia glabra) leaf powder.http://dx.doi.org/10.1155/2010/938692
spellingShingle T. Mugugan
A. Ganapathi
R. Valliappan
Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
E-Journal of Chemistry
title Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
title_full Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
title_fullStr Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
title_full_unstemmed Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
title_short Removal of Grey BL from Dye Wastewater by Derris (Pongamia Glabra) Leaf Powder by Adsorption
title_sort removal of grey bl from dye wastewater by derris pongamia glabra leaf powder by adsorption
url http://dx.doi.org/10.1155/2010/938692
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AT aganapathi removalofgreyblfromdyewastewaterbyderrispongamiaglabraleafpowderbyadsorption
AT rvalliappan removalofgreyblfromdyewastewaterbyderrispongamiaglabraleafpowderbyadsorption