In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method

Carbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel...

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Main Authors: Wei Yang, Haifeng Dang, Shengzhou Chen, Hanbo Zou, Zili Liu, Jing Lin, Weiming Lin
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2016/4279457
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author Wei Yang
Haifeng Dang
Shengzhou Chen
Hanbo Zou
Zili Liu
Jing Lin
Weiming Lin
author_facet Wei Yang
Haifeng Dang
Shengzhou Chen
Hanbo Zou
Zili Liu
Jing Lin
Weiming Lin
author_sort Wei Yang
collection DOAJ
description Carbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel manganese oxide has the cubic face-centered spinel structure with a space group of Fd3m. It showed good electrochemical performance as a cathode material for lithium ion battery. After 100 discharge and charge cycles at 0.5 C rate, the specific discharge capacity of carbon coated LiNi0.5Mn1.5O4 was 130 mAh·g−1, and the corresponding capacity retention was 98.8%. The 100th cycle specific discharge capacity at 10 C rate of carbon coated LiNi0.5Mn1.5O4 was 105.4 mAh·g−1, and even the corresponding capacity retention was 95.2%.
format Article
id doaj-art-18f6dc19373c4b8aa2dab8eb57ca059c
institution Kabale University
issn 1687-9422
1687-9430
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-18f6dc19373c4b8aa2dab8eb57ca059c2025-02-03T01:02:06ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/42794574279457In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted MethodWei Yang0Haifeng Dang1Shengzhou Chen2Hanbo Zou3Zili Liu4Jing Lin5Weiming Lin6School of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Environmental Engineering, Dongguan University of Technology, Dongguan 523808, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaCarbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel manganese oxide has the cubic face-centered spinel structure with a space group of Fd3m. It showed good electrochemical performance as a cathode material for lithium ion battery. After 100 discharge and charge cycles at 0.5 C rate, the specific discharge capacity of carbon coated LiNi0.5Mn1.5O4 was 130 mAh·g−1, and the corresponding capacity retention was 98.8%. The 100th cycle specific discharge capacity at 10 C rate of carbon coated LiNi0.5Mn1.5O4 was 105.4 mAh·g−1, and even the corresponding capacity retention was 95.2%.http://dx.doi.org/10.1155/2016/4279457
spellingShingle Wei Yang
Haifeng Dang
Shengzhou Chen
Hanbo Zou
Zili Liu
Jing Lin
Weiming Lin
In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
International Journal of Polymer Science
title In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
title_full In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
title_fullStr In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
title_full_unstemmed In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
title_short In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
title_sort in situ carbon coated lini0 5mn1 5o4 cathode material prepared by prepolymer of melamine formaldehyde resin assisted method
url http://dx.doi.org/10.1155/2016/4279457
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