In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method
Carbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel...
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Format: | Article |
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Wiley
2016-01-01
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Series: | International Journal of Polymer Science |
Online Access: | http://dx.doi.org/10.1155/2016/4279457 |
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author | Wei Yang Haifeng Dang Shengzhou Chen Hanbo Zou Zili Liu Jing Lin Weiming Lin |
author_facet | Wei Yang Haifeng Dang Shengzhou Chen Hanbo Zou Zili Liu Jing Lin Weiming Lin |
author_sort | Wei Yang |
collection | DOAJ |
description | Carbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel manganese oxide has the cubic face-centered spinel structure with a space group of Fd3m. It showed good electrochemical performance as a cathode material for lithium ion battery. After 100 discharge and charge cycles at 0.5 C rate, the specific discharge capacity of carbon coated LiNi0.5Mn1.5O4 was 130 mAh·g−1, and the corresponding capacity retention was 98.8%. The 100th cycle specific discharge capacity at 10 C rate of carbon coated LiNi0.5Mn1.5O4 was 105.4 mAh·g−1, and even the corresponding capacity retention was 95.2%. |
format | Article |
id | doaj-art-18f6dc19373c4b8aa2dab8eb57ca059c |
institution | Kabale University |
issn | 1687-9422 1687-9430 |
language | English |
publishDate | 2016-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Polymer Science |
spelling | doaj-art-18f6dc19373c4b8aa2dab8eb57ca059c2025-02-03T01:02:06ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/42794574279457In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted MethodWei Yang0Haifeng Dang1Shengzhou Chen2Hanbo Zou3Zili Liu4Jing Lin5Weiming Lin6School of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Environmental Engineering, Dongguan University of Technology, Dongguan 523808, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaSchool of Chemistry and Chemical Engineering, Guangzhou University, 230 Waihuanxi Road, Panyu District, Guangzhou 510006, ChinaCarbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel manganese oxide has the cubic face-centered spinel structure with a space group of Fd3m. It showed good electrochemical performance as a cathode material for lithium ion battery. After 100 discharge and charge cycles at 0.5 C rate, the specific discharge capacity of carbon coated LiNi0.5Mn1.5O4 was 130 mAh·g−1, and the corresponding capacity retention was 98.8%. The 100th cycle specific discharge capacity at 10 C rate of carbon coated LiNi0.5Mn1.5O4 was 105.4 mAh·g−1, and even the corresponding capacity retention was 95.2%.http://dx.doi.org/10.1155/2016/4279457 |
spellingShingle | Wei Yang Haifeng Dang Shengzhou Chen Hanbo Zou Zili Liu Jing Lin Weiming Lin In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method International Journal of Polymer Science |
title | In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method |
title_full | In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method |
title_fullStr | In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method |
title_full_unstemmed | In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method |
title_short | In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method |
title_sort | in situ carbon coated lini0 5mn1 5o4 cathode material prepared by prepolymer of melamine formaldehyde resin assisted method |
url | http://dx.doi.org/10.1155/2016/4279457 |
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