Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks

In order to meet the demand for the identification and detection of high-risk environmental pollutants in industrial park tail water, this paper adopted the gas chromatography-mass spectrometry (GC-MS) method to achieve the rapid qualitative analysis of alkanes, olefins, benzenes, ketones, alcohols,...

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Main Authors: YANG Lei, FU Ruotong, JIN Wenhui, FU Shiying, SHAO Zhen, WANG Xueting, CHEN Chuan*
Format: Article
Language:zho
Published: Editorial Office of Energy Environmental Protection 2024-02-01
Series:能源环境保护
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Online Access:https://eep1987.com/en/article/4797
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author YANG Lei
FU Ruotong
JIN Wenhui
FU Shiying
SHAO Zhen
WANG Xueting
CHEN Chuan*
author_facet YANG Lei
FU Ruotong
JIN Wenhui
FU Shiying
SHAO Zhen
WANG Xueting
CHEN Chuan*
author_sort YANG Lei
collection DOAJ
description In order to meet the demand for the identification and detection of high-risk environmental pollutants in industrial park tail water, this paper adopted the gas chromatography-mass spectrometry (GC-MS) method to achieve the rapid qualitative analysis of alkanes, olefins, benzenes, ketones, alcohols, esters, acids, and other organics in the tail water of chemical/ pharmaceutical industrial parks. Based on the production process and water quality research and analysis of key enterprises within the industrial park, typical organic compounds, including 3-hexanol, 3-hexanone, methyl 3-(3,5-di-tertbutyl-4-hydroxyphenyl) propionate, and 4-bromo-2,6-di-tert-butylphenol were selected. A high-performance liquid chromatography (HPLC) method was established to analyze these compounds in the tail water achieving recoveries of 80% to 97% and the average recoveries of 87% to 95%. Furthermore aerobic and anaerobic biological sequential batch experiments were conducted to verify the biodegradation effect of these typical organics. The results showed that aerobic treatment was more effective than anaerobic treatment, with concentration removal rates ranging from 48.0% to 88.8%, COD removal rates from 70.8% to 99.9%, and average TOC removal rates from 54.7% to 79.5%. These findings provide theoretical and technological support for the further studies on advanced treatment technology or the upgrading and transformation of processes for industrial wastewater.
format Article
id doaj-art-18d2b8fca6cf4f009ed8667dd0a2f5f0
institution Kabale University
issn 2097-4183
language zho
publishDate 2024-02-01
publisher Editorial Office of Energy Environmental Protection
record_format Article
series 能源环境保护
spelling doaj-art-18d2b8fca6cf4f009ed8667dd0a2f5f02025-01-24T06:35:49ZzhoEditorial Office of Energy Environmental Protection能源环境保护2097-41832024-02-01381657510.20078/j.eep.20240111Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parksYANG Lei 0FU Ruotong1JIN Wenhui2FU Shiying3SHAO Zhen4WANG Xueting5CHEN Chuan*6School of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologySchool of Environment, Harbin Institute of TechnologyIn order to meet the demand for the identification and detection of high-risk environmental pollutants in industrial park tail water, this paper adopted the gas chromatography-mass spectrometry (GC-MS) method to achieve the rapid qualitative analysis of alkanes, olefins, benzenes, ketones, alcohols, esters, acids, and other organics in the tail water of chemical/ pharmaceutical industrial parks. Based on the production process and water quality research and analysis of key enterprises within the industrial park, typical organic compounds, including 3-hexanol, 3-hexanone, methyl 3-(3,5-di-tertbutyl-4-hydroxyphenyl) propionate, and 4-bromo-2,6-di-tert-butylphenol were selected. A high-performance liquid chromatography (HPLC) method was established to analyze these compounds in the tail water achieving recoveries of 80% to 97% and the average recoveries of 87% to 95%. Furthermore aerobic and anaerobic biological sequential batch experiments were conducted to verify the biodegradation effect of these typical organics. The results showed that aerobic treatment was more effective than anaerobic treatment, with concentration removal rates ranging from 48.0% to 88.8%, COD removal rates from 70.8% to 99.9%, and average TOC removal rates from 54.7% to 79.5%. These findings provide theoretical and technological support for the further studies on advanced treatment technology or the upgrading and transformation of processes for industrial wastewater.https://eep1987.com/en/article/4797industrial wastewatertypical organic compoundsgas chromatography-mass spectrometryhigh performance liquid chromatographybiological treatment
spellingShingle YANG Lei
FU Ruotong
JIN Wenhui
FU Shiying
SHAO Zhen
WANG Xueting
CHEN Chuan*
Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
能源环境保护
industrial wastewater
typical organic compounds
gas chromatography-mass spectrometry
high performance liquid chromatography
biological treatment
title Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
title_full Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
title_fullStr Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
title_full_unstemmed Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
title_short Detection methods and biological treatment of typical organic compounds in tail water of chemical/pharmaceutical industrial parks
title_sort detection methods and biological treatment of typical organic compounds in tail water of chemical pharmaceutical industrial parks
topic industrial wastewater
typical organic compounds
gas chromatography-mass spectrometry
high performance liquid chromatography
biological treatment
url https://eep1987.com/en/article/4797
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AT furuotong detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks
AT jinwenhui detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks
AT fushiying detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks
AT shaozhen detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks
AT wangxueting detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks
AT chenchuan detectionmethodsandbiologicaltreatmentoftypicalorganiccompoundsintailwaterofchemicalpharmaceuticalindustrialparks