Self-diffusion anomalies of an odd tracer in soft-core media

Odd-diffusive systems, characterised by broken time-reversal and/or parity, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we extend the investigation to the high-density limit of an odd tracer embedded in a soft medium d...

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Bibliographic Details
Main Authors: Pietro Luigi Muzzeddu, Erik Kalz, Andrea Gambassi, Abhinav Sharma, Ralf Metzler
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:New Journal of Physics
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Online Access:https://doi.org/10.1088/1367-2630/adbdea
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Summary:Odd-diffusive systems, characterised by broken time-reversal and/or parity, have recently been shown to display counterintuitive features such as interaction-enhanced dynamics in the dilute limit. Here we extend the investigation to the high-density limit of an odd tracer embedded in a soft medium described by the Gaussian core model (GCM) using a field-theoretic approach based on the Dean–Kawasaki equation. Our analysis reveals that interactions can enhance the dynamics of an odd tracer even in dense systems. We demonstrate that oddness results in a complete reversal of the well-known self-diffusion ( $D_\mathrm{s}$ ) anomaly of the GCM. Ordinarily, $D_\mathrm{s}$ exhibits a non-monotonic trend with increasing density, approaching but remaining below the interaction-free diffusion, D _0 , ( $D_\mathrm{s} \lt D_0$ ) so that $D_\mathrm{s} \uparrow D_0$ at high densities. In contrast, for an odd tracer, self-diffusion is enhanced ( $D_\mathrm{s} \gt D_0$ ) and the GCM anomaly is inverted, displaying $D_\mathrm{s} \downarrow D_0$ at high densities. The transition between the standard and reversed GCM anomaly is governed by the tracer’s oddness, with a critical oddness value at which the tracer diffuses as a free particle ( $D_\mathrm{s} \approx D_0$ ) across all densities. We validate our theoretical predictions with Brownian dynamics simulations, finding strong agreement between the them.
ISSN:1367-2630