XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation

XPS and GDOES characterizations of porous coatings on tantalum after Plasma Electrolytic Oxidation (PEO) at 450 V for 3 minutes in electrolyte containing concentrated (85%) phosphoric acid with calcium nitrate and copper (II) nitrate are described. Based on the obtained data, it may be concluded tha...

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Main Authors: Krzysztof Rokosz, Tadeusz Hryniewicz, Patrick Chapon, Steinar Raaen, Hugo Ricardo Zschommler Sandim
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2016/7093071
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author Krzysztof Rokosz
Tadeusz Hryniewicz
Patrick Chapon
Steinar Raaen
Hugo Ricardo Zschommler Sandim
author_facet Krzysztof Rokosz
Tadeusz Hryniewicz
Patrick Chapon
Steinar Raaen
Hugo Ricardo Zschommler Sandim
author_sort Krzysztof Rokosz
collection DOAJ
description XPS and GDOES characterizations of porous coatings on tantalum after Plasma Electrolytic Oxidation (PEO) at 450 V for 3 minutes in electrolyte containing concentrated (85%) phosphoric acid with calcium nitrate and copper (II) nitrate are described. Based on the obtained data, it may be concluded that the PEO coating consists of tantalum (Ta5+), calcium (Ca2+), copper (Cu2+  and Cu+), and phosphates (PO43-). It has to be pointed out that copper and calcium are distributed throughout the volume. The authors also propose a new model of PEO, based on the derivative of GDOES signals with sputtering time.
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institution Kabale University
issn 2314-4920
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language English
publishDate 2016-01-01
publisher Wiley
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series Journal of Spectroscopy
spelling doaj-art-17ee20b65c66487a9686c3449c32ba432025-02-03T01:02:28ZengWileyJournal of Spectroscopy2314-49202314-49392016-01-01201610.1155/2016/70930717093071XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic OxidationKrzysztof Rokosz0Tadeusz Hryniewicz1Patrick Chapon2Steinar Raaen3Hugo Ricardo Zschommler Sandim4Division of Bioengineering and Surface Electrochemistry, Department of Engineering and Informatics Systems, Faculty of Mechanical Engineering, Koszalin University of Technology, Racławicka 15-17, 75-620 Koszalin, PolandDivision of Bioengineering and Surface Electrochemistry, Department of Engineering and Informatics Systems, Faculty of Mechanical Engineering, Koszalin University of Technology, Racławicka 15-17, 75-620 Koszalin, PolandHORIBA Jobin Yvon S.A.S., 16-18 rue du Canal, 91165 Longjumeau Cedex, FranceDepartment of Physics, Norwegian University of Science and Technology (NTNU), Realfagbygget E3-124 Høgskoleringen 5, 7491 Trondheim, NorwayDepartment of Materials Engineering, Lorena School of Engineering, University of Sao Paulo, 12602-810 Lorena, SP, BrazilXPS and GDOES characterizations of porous coatings on tantalum after Plasma Electrolytic Oxidation (PEO) at 450 V for 3 minutes in electrolyte containing concentrated (85%) phosphoric acid with calcium nitrate and copper (II) nitrate are described. Based on the obtained data, it may be concluded that the PEO coating consists of tantalum (Ta5+), calcium (Ca2+), copper (Cu2+  and Cu+), and phosphates (PO43-). It has to be pointed out that copper and calcium are distributed throughout the volume. The authors also propose a new model of PEO, based on the derivative of GDOES signals with sputtering time.http://dx.doi.org/10.1155/2016/7093071
spellingShingle Krzysztof Rokosz
Tadeusz Hryniewicz
Patrick Chapon
Steinar Raaen
Hugo Ricardo Zschommler Sandim
XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
Journal of Spectroscopy
title XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
title_full XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
title_fullStr XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
title_full_unstemmed XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
title_short XPS and GDOES Characterization of Porous Coating Enriched with Copper and Calcium Obtained on Tantalum via Plasma Electrolytic Oxidation
title_sort xps and gdoes characterization of porous coating enriched with copper and calcium obtained on tantalum via plasma electrolytic oxidation
url http://dx.doi.org/10.1155/2016/7093071
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