Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid

Ground rice husks were impregnated with phosphoric acid (30–70 wt.%) followed by carbonization at 673 or 773 K. Analysis of the nitrogen adsorption isotherms was achieved by applying the BET, DR, t- and α S -methods so as to assess the contribution of micropores and mesopores in the products. The wa...

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Main Author: Laila B. Khalil
Format: Article
Language:English
Published: SAGE Publishing 1996-10-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749601300502
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author Laila B. Khalil
author_facet Laila B. Khalil
author_sort Laila B. Khalil
collection DOAJ
description Ground rice husks were impregnated with phosphoric acid (30–70 wt.%) followed by carbonization at 673 or 773 K. Analysis of the nitrogen adsorption isotherms was achieved by applying the BET, DR, t- and α S -methods so as to assess the contribution of micropores and mesopores in the products. The washed products showed reasonable surface areas with dimensions in the micropore range. Adsorption of methylene blue from aqueous solution indicated high affinity and high dye removal capacity. Low iodine numbers and methylene blue values were ascribed to the high ash content extending up to 50% of the activated carbon. Pre-impregnation with 50% H 3 PO 4 and carbonization at 400°C proved to be most effective in producing an activated carbon with the highest adsorption capacity from the gas or solution.
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institution Kabale University
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2048-4038
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publishDate 1996-10-01
publisher SAGE Publishing
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series Adsorption Science & Technology
spelling doaj-art-166796554c52440098561722a3359fcb2025-02-03T10:13:00ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381996-10-011310.1177/026361749601300502Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric AcidLaila B. Khalil0Laboratory of Surface Chemistry and Catalysis, National Research Centre, Dokki, Cairo, Egypt.Ground rice husks were impregnated with phosphoric acid (30–70 wt.%) followed by carbonization at 673 or 773 K. Analysis of the nitrogen adsorption isotherms was achieved by applying the BET, DR, t- and α S -methods so as to assess the contribution of micropores and mesopores in the products. The washed products showed reasonable surface areas with dimensions in the micropore range. Adsorption of methylene blue from aqueous solution indicated high affinity and high dye removal capacity. Low iodine numbers and methylene blue values were ascribed to the high ash content extending up to 50% of the activated carbon. Pre-impregnation with 50% H 3 PO 4 and carbonization at 400°C proved to be most effective in producing an activated carbon with the highest adsorption capacity from the gas or solution.https://doi.org/10.1177/026361749601300502
spellingShingle Laila B. Khalil
Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
Adsorption Science & Technology
title Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
title_full Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
title_fullStr Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
title_full_unstemmed Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
title_short Adsorption Characteristics of Activated Carbon Obtained from Rice Husks by Treatment with Phosphoric Acid
title_sort adsorption characteristics of activated carbon obtained from rice husks by treatment with phosphoric acid
url https://doi.org/10.1177/026361749601300502
work_keys_str_mv AT lailabkhalil adsorptioncharacteristicsofactivatedcarbonobtainedfromricehusksbytreatmentwithphosphoricacid