Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer
Low efficiency of conventional fertilizer (quick release fertilizer) application in agricultural sectors has caused environmental pollution and health problems. A method to overcome the drawback of the conventional fertilizer is by controlled release fertilizer (CRF) preparation. CRF is expected to...
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| Format: | Article |
| Language: | English |
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Wiley
2019-01-01
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| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2019/2958021 |
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| author | Yuni Kusumastuti Alit Istiani Rochmadi Chandra Wahyu Purnomo |
| author_facet | Yuni Kusumastuti Alit Istiani Rochmadi Chandra Wahyu Purnomo |
| author_sort | Yuni Kusumastuti |
| collection | DOAJ |
| description | Low efficiency of conventional fertilizer (quick release fertilizer) application in agricultural sectors has caused environmental pollution and health problems. A method to overcome the drawback of the conventional fertilizer is by controlled release fertilizer (CRF) preparation. CRF is expected to be able to fulfil the nutrient demand of targeted plants. The objective of this research is to prepare CRF by coating NPK fertilizer with multilayer chitosan-polyanion using alginate, pectin, and sodium tripolyphosphate (TPP). In addition, the effect of the layer arrangement modification of material on the rate of nitrogen release was also studied. The mechanical strength of coated fertilizer was analysed by compressive stress test and the properties of the fertilizer coating was observed by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The nitrogen release study shows that multilayer of chitosan-alginate (CA)5, chitosan-pectin (CP)5, and chitosan-TPP (CT)5 as coating material was able to increase the compressive stress and decrease the nitrogen release of coated fertilizer. These results are supported by the FTIR analysis which exhibits the formation of ionic interaction between amine group of chitosan and carboxyl group of alginate in chitosan-alginate (CA)5 layer, carboxyl group of pectin in chitosan-pectin (CP)5 layer, and phosphate of TPP in chitosan-TPP (CT)5 layer. On the other hand, the modification of the arrangement of chitosan-alginate layers showed that the fertilizer with the alternating layer arrangement (CA)5 was able to optimally increase the compressive strength. The mathematical model for the nitrogen release of coated fertilizer is also prepared and simulated with the MATLAB software. The simulation results showed that the nitrogen release of coated fertilizer followed the proposed diffusion mechanism. The obtained diffusivity coefficient value in the layer of chitosan-alginate (CA)5 is 2.0933 × 10−6 cm2/s, 2.5606 × 10−6 cm2/s in chitosan-TPP (CT)5 layer, and 3.7256 × 10−6 cm2/s in chitosan-pectin (CP)5 layer. |
| format | Article |
| id | doaj-art-1591ed8ca80245b8af159dc022b607c5 |
| institution | Kabale University |
| issn | 1687-8434 1687-8442 |
| language | English |
| publishDate | 2019-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Materials Science and Engineering |
| spelling | doaj-art-1591ed8ca80245b8af159dc022b607c52025-02-03T05:53:17ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422019-01-01201910.1155/2019/29580212958021Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released FertilizerYuni Kusumastuti0Alit Istiani1Rochmadi2Chandra Wahyu Purnomo3Department of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, IndonesiaDepartment of Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Yogyakarta, IndonesiaLow efficiency of conventional fertilizer (quick release fertilizer) application in agricultural sectors has caused environmental pollution and health problems. A method to overcome the drawback of the conventional fertilizer is by controlled release fertilizer (CRF) preparation. CRF is expected to be able to fulfil the nutrient demand of targeted plants. The objective of this research is to prepare CRF by coating NPK fertilizer with multilayer chitosan-polyanion using alginate, pectin, and sodium tripolyphosphate (TPP). In addition, the effect of the layer arrangement modification of material on the rate of nitrogen release was also studied. The mechanical strength of coated fertilizer was analysed by compressive stress test and the properties of the fertilizer coating was observed by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The nitrogen release study shows that multilayer of chitosan-alginate (CA)5, chitosan-pectin (CP)5, and chitosan-TPP (CT)5 as coating material was able to increase the compressive stress and decrease the nitrogen release of coated fertilizer. These results are supported by the FTIR analysis which exhibits the formation of ionic interaction between amine group of chitosan and carboxyl group of alginate in chitosan-alginate (CA)5 layer, carboxyl group of pectin in chitosan-pectin (CP)5 layer, and phosphate of TPP in chitosan-TPP (CT)5 layer. On the other hand, the modification of the arrangement of chitosan-alginate layers showed that the fertilizer with the alternating layer arrangement (CA)5 was able to optimally increase the compressive strength. The mathematical model for the nitrogen release of coated fertilizer is also prepared and simulated with the MATLAB software. The simulation results showed that the nitrogen release of coated fertilizer followed the proposed diffusion mechanism. The obtained diffusivity coefficient value in the layer of chitosan-alginate (CA)5 is 2.0933 × 10−6 cm2/s, 2.5606 × 10−6 cm2/s in chitosan-TPP (CT)5 layer, and 3.7256 × 10−6 cm2/s in chitosan-pectin (CP)5 layer.http://dx.doi.org/10.1155/2019/2958021 |
| spellingShingle | Yuni Kusumastuti Alit Istiani Rochmadi Chandra Wahyu Purnomo Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer Advances in Materials Science and Engineering |
| title | Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer |
| title_full | Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer |
| title_fullStr | Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer |
| title_full_unstemmed | Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer |
| title_short | Chitosan-Based Polyion Multilayer Coating on NPK Fertilizer as Controlled Released Fertilizer |
| title_sort | chitosan based polyion multilayer coating on npk fertilizer as controlled released fertilizer |
| url | http://dx.doi.org/10.1155/2019/2958021 |
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