Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems

Phase compositions of B-Fe-Mn-V alloys were studied by several experimental methods (DTA measurement, X-ray diffractions, and scanning electron microscopy). Besides the experimental study of the quaternary system, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method and thermod...

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Main Authors: Viera Homolová, Ján Kepič, Adéla Zemanová, Ondřej Zobač
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/3950980
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author Viera Homolová
Ján Kepič
Adéla Zemanová
Ondřej Zobač
author_facet Viera Homolová
Ján Kepič
Adéla Zemanová
Ondřej Zobač
author_sort Viera Homolová
collection DOAJ
description Phase compositions of B-Fe-Mn-V alloys were studied by several experimental methods (DTA measurement, X-ray diffractions, and scanning electron microscopy). Besides the experimental study of the quaternary system, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method and thermodynamic calculations for the quaternary B-Fe-Mn-V system were performed. Calculations for the quaternary system are based on the ternary subsystems (B-Mn-V, B-Fe-V, B-Fe-Mn, and Fe-Mn-V). Boron is modelled as an interstitial element in all solid solutions of vanadium, manganese, and iron. Very good agreement between experimental results and thermodynamic calculations was achieved. The created thermodynamic database is suitable for thermodynamic calculations of phase diagrams for all the ternary subsystems and also for the B-Fe-Mn-V quaternary system.
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institution Kabale University
issn 1687-8434
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language English
publishDate 2018-01-01
publisher Wiley
record_format Article
series Advances in Materials Science and Engineering
spelling doaj-art-14b97ae6d5f94d7dbffbb82f13f0ce212025-02-03T01:29:23ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/39509803950980Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V SystemsViera Homolová0Ján Kepič1Adéla Zemanová2Ondřej Zobač3Institute of Materials Research, Slovak Academy of Sciences, Watsonova 47, 040 01 Košice, SlovakiaInstitute of Materials Research, Slovak Academy of Sciences, Watsonova 47, 040 01 Košice, SlovakiaInstitute of Physics of Materials, Academy of Sciences of the Czech Republic, Žižkova 22, 616 62 Brno, Czech RepublicInstitute of Physics of Materials, Academy of Sciences of the Czech Republic, Žižkova 22, 616 62 Brno, Czech RepublicPhase compositions of B-Fe-Mn-V alloys were studied by several experimental methods (DTA measurement, X-ray diffractions, and scanning electron microscopy). Besides the experimental study of the quaternary system, thermodynamic modelling of the ternary B-Mn-V system by the Calphad method and thermodynamic calculations for the quaternary B-Fe-Mn-V system were performed. Calculations for the quaternary system are based on the ternary subsystems (B-Mn-V, B-Fe-V, B-Fe-Mn, and Fe-Mn-V). Boron is modelled as an interstitial element in all solid solutions of vanadium, manganese, and iron. Very good agreement between experimental results and thermodynamic calculations was achieved. The created thermodynamic database is suitable for thermodynamic calculations of phase diagrams for all the ternary subsystems and also for the B-Fe-Mn-V quaternary system.http://dx.doi.org/10.1155/2018/3950980
spellingShingle Viera Homolová
Ján Kepič
Adéla Zemanová
Ondřej Zobač
Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
Advances in Materials Science and Engineering
title Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
title_full Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
title_fullStr Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
title_full_unstemmed Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
title_short Experimental Study of Phase Composition of B-Fe-Mn-V Alloys and Thermodynamic Calculations of Phase Equilibria in the B-Mn-V and B-Fe-Mn-V Systems
title_sort experimental study of phase composition of b fe mn v alloys and thermodynamic calculations of phase equilibria in the b mn v and b fe mn v systems
url http://dx.doi.org/10.1155/2018/3950980
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