Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates
New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar=o-,m-,p-CH3C6H4 and p-Cl-m-CH3C6H3; n=1, L = N2C12H8, N2C10H8; n=2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar condu...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2013/261731 |
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| author | Ruchi Khajuria Atiya Syed Sandeep Kumar Sushil K. Pandey |
| author_facet | Ruchi Khajuria Atiya Syed Sandeep Kumar Sushil K. Pandey |
| author_sort | Ruchi Khajuria |
| collection | DOAJ |
| description | New complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar=o-,m-,p-CH3C6H4 and p-Cl-m-CH3C6H3; n=1, L = N2C12H8, N2C10H8; n=2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, thermogravimetric, cyclic voltammetry, and spectral analyses including ESI mass spectrometry, IR, and UV-visible. The presence of a four-and-six coordinated Mn atoms has been established in the complexes and adducts, respectively. Antimicrobial screening of the complexes against gram negative bacteria E. coli, K. pneumonia, and P. aeruginosa and fungus S. rolfsii has shown potential bioactivity. |
| format | Article |
| id | doaj-art-13fcd2226c2845758079864982db5f58 |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-13fcd2226c2845758079864982db5f582025-02-03T01:12:08ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2013-01-01201310.1155/2013/261731261731Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) DitolyldithiophosphatesRuchi Khajuria0Atiya Syed1Sandeep Kumar2Sushil K. Pandey3Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu and Kashmir 180 006, IndiaDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu and Kashmir 180 006, IndiaDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu and Kashmir 180 006, IndiaDepartment of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu and Kashmir 180 006, IndiaNew complexes of manganese(II) corresponding to [{(ArO)2PS2}2Mn] and [{(ArO)2PS2}2Mn.nL] (Ar=o-,m-,p-CH3C6H4 and p-Cl-m-CH3C6H3; n=1, L = N2C12H8, N2C10H8; n=2, L = NC5H5, P(C6H5)3) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, thermogravimetric, cyclic voltammetry, and spectral analyses including ESI mass spectrometry, IR, and UV-visible. The presence of a four-and-six coordinated Mn atoms has been established in the complexes and adducts, respectively. Antimicrobial screening of the complexes against gram negative bacteria E. coli, K. pneumonia, and P. aeruginosa and fungus S. rolfsii has shown potential bioactivity.http://dx.doi.org/10.1155/2013/261731 |
| spellingShingle | Ruchi Khajuria Atiya Syed Sandeep Kumar Sushil K. Pandey Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates Bioinorganic Chemistry and Applications |
| title | Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates |
| title_full | Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates |
| title_fullStr | Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates |
| title_full_unstemmed | Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates |
| title_short | Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates |
| title_sort | spectroscopic thermal electrochemical and antimicrobial studies of mononuclear manganese ii ditolyldithiophosphates |
| url | http://dx.doi.org/10.1155/2013/261731 |
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