NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption

NaY zeolite in this study is novelly synthesized from rice husk ash with a one-stage process instead of passing the solid silica recovery process as usual. NaY zeolite applies to assess adsorption ability of chromium(VI) ions in water with varying key factors. The as-synthesized zeolite is characte...

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Main Authors: Huynh Vu Thanh Luong, Hoang Ngoan Nguyen, Thi Kim Thu Pham, Thanh Phu Le, Tran Lan Trinh Le, Huynh Giao Dang, Thi Bich Quyen Tran
Format: Article
Language:English
Published: Can Tho University Publisher 2024-03-01
Series:CTU Journal of Innovation and Sustainable Development
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Online Access:https://ctujs.ctu.edu.vn/index.php/ctujs/article/view/673
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author Huynh Vu Thanh Luong
Hoang Ngoan Nguyen
Thi Kim Thu Pham
Thanh Phu Le
Tran Lan Trinh Le
Huynh Giao Dang
Thi Bich Quyen Tran
author_facet Huynh Vu Thanh Luong
Hoang Ngoan Nguyen
Thi Kim Thu Pham
Thanh Phu Le
Tran Lan Trinh Le
Huynh Giao Dang
Thi Bich Quyen Tran
author_sort Huynh Vu Thanh Luong
collection DOAJ
description NaY zeolite in this study is novelly synthesized from rice husk ash with a one-stage process instead of passing the solid silica recovery process as usual. NaY zeolite applies to assess adsorption ability of chromium(VI) ions in water with varying key factors. The as-synthesized zeolite is characterized by X-ray diffraction, X-ray fluorescence, scanning electron microscope, specific surface area analysis and inductively coupled plasma mass spectrometry with optical emission spectroscopy. As a result, the optimal conditions for silica extraction are at 90oC with a NaOH concentration of 4 M for 4 h with recovery efficiency 87.5%. NaY zeolite is successfully synthesized with Si/Al ratio of 10, aging time of 24 h and crystallization time of 24 h with synthesis yield of 31.25% and crystallinity of 96%. The optimal conditions for the chromium(VI) adsorption in aqueous solution are at pH 2.0, adsorption time of 120 min, initial concentration of 20 mg/L with an adsorbent mass of 0.1 g. The kinetics and adsorption isotherms show a good agreement with pseudo-second order and Freundlich adsorption isotherm model. NaY zeolite is synthesized via environmentally friendly approach with time and energy savings and shows its high adsorb-ability of chromium(VI) in water.
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issn 2588-1418
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language English
publishDate 2024-03-01
publisher Can Tho University Publisher
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spelling doaj-art-13df9fbd2b4c48bfa14f443bd501ea1a2025-08-20T02:16:49ZengCan Tho University PublisherCTU Journal of Innovation and Sustainable Development2588-14182815-64122024-03-0116110.22144/ctujoisd.2024.261NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorptionHuynh Vu Thanh Luong0Hoang Ngoan NguyenThi Kim Thu PhamThanh Phu LeTran Lan Trinh LeHuynh Giao DangThi Bich Quyen TranBM.Cong nghe Hoa hoc, Khoa Công nghệ NaY zeolite in this study is novelly synthesized from rice husk ash with a one-stage process instead of passing the solid silica recovery process as usual. NaY zeolite applies to assess adsorption ability of chromium(VI) ions in water with varying key factors. The as-synthesized zeolite is characterized by X-ray diffraction, X-ray fluorescence, scanning electron microscope, specific surface area analysis and inductively coupled plasma mass spectrometry with optical emission spectroscopy. As a result, the optimal conditions for silica extraction are at 90oC with a NaOH concentration of 4 M for 4 h with recovery efficiency 87.5%. NaY zeolite is successfully synthesized with Si/Al ratio of 10, aging time of 24 h and crystallization time of 24 h with synthesis yield of 31.25% and crystallinity of 96%. The optimal conditions for the chromium(VI) adsorption in aqueous solution are at pH 2.0, adsorption time of 120 min, initial concentration of 20 mg/L with an adsorbent mass of 0.1 g. The kinetics and adsorption isotherms show a good agreement with pseudo-second order and Freundlich adsorption isotherm model. NaY zeolite is synthesized via environmentally friendly approach with time and energy savings and shows its high adsorb-ability of chromium(VI) in water. https://ctujs.ctu.edu.vn/index.php/ctujs/article/view/673Adsorbent, adsorption, chromium (VI), NaY zeolite, rice husk ash
spellingShingle Huynh Vu Thanh Luong
Hoang Ngoan Nguyen
Thi Kim Thu Pham
Thanh Phu Le
Tran Lan Trinh Le
Huynh Giao Dang
Thi Bich Quyen Tran
NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
CTU Journal of Innovation and Sustainable Development
Adsorbent, adsorption, chromium (VI), NaY zeolite, rice husk ash
title NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
title_full NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
title_fullStr NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
title_full_unstemmed NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
title_short NaY zeolite synthesis from rice husk ash for Chromium(VI) ion adsorption
title_sort nay zeolite synthesis from rice husk ash for chromium vi ion adsorption
topic Adsorbent, adsorption, chromium (VI), NaY zeolite, rice husk ash
url https://ctujs.ctu.edu.vn/index.php/ctujs/article/view/673
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