Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition

Germanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increas...

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Main Authors: Ayu Enomoto, Atsushi Suzuki, Takeo Oku, Haruto Shimada
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Inorganics
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Online Access:https://www.mdpi.com/2304-6740/13/1/15
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author Ayu Enomoto
Atsushi Suzuki
Takeo Oku
Haruto Shimada
author_facet Ayu Enomoto
Atsushi Suzuki
Takeo Oku
Haruto Shimada
author_sort Ayu Enomoto
collection DOAJ
description Germanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increased by increasing the Ge contents. The highest conversion efficiency of 6.05% was obtained for the 12.5% Ge added device in an air atmosphere and the increase of efficiencies would be due to the promoted formation of photoactive α-formamidinium cesium lead triiodide perovskite crystals.
format Article
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institution Kabale University
issn 2304-6740
language English
publishDate 2025-01-01
publisher MDPI AG
record_format Article
series Inorganics
spelling doaj-art-133528490dd74fd798f3ffd852a39a532025-01-24T13:35:29ZengMDPI AGInorganics2304-67402025-01-011311510.3390/inorganics13010015Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium AdditionAyu Enomoto0Atsushi Suzuki1Takeo Oku2Haruto Shimada3Department of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanGermanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increased by increasing the Ge contents. The highest conversion efficiency of 6.05% was obtained for the 12.5% Ge added device in an air atmosphere and the increase of efficiencies would be due to the promoted formation of photoactive α-formamidinium cesium lead triiodide perovskite crystals.https://www.mdpi.com/2304-6740/13/1/15perovskite solar cellgermaniumFAPbI<sub>3</sub>first principle calculation
spellingShingle Ayu Enomoto
Atsushi Suzuki
Takeo Oku
Haruto Shimada
Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
Inorganics
perovskite solar cell
germanium
FAPbI<sub>3</sub>
first principle calculation
title Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
title_full Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
title_fullStr Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
title_full_unstemmed Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
title_short Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
title_sort promoted formation of photoactive α formamidinium cesium lead triiodide perovskite crystals by germanium addition
topic perovskite solar cell
germanium
FAPbI<sub>3</sub>
first principle calculation
url https://www.mdpi.com/2304-6740/13/1/15
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AT atsushisuzuki promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition
AT takeooku promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition
AT harutoshimada promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition