Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition
Germanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increas...
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2025-01-01
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author | Ayu Enomoto Atsushi Suzuki Takeo Oku Haruto Shimada |
author_facet | Ayu Enomoto Atsushi Suzuki Takeo Oku Haruto Shimada |
author_sort | Ayu Enomoto |
collection | DOAJ |
description | Germanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increased by increasing the Ge contents. The highest conversion efficiency of 6.05% was obtained for the 12.5% Ge added device in an air atmosphere and the increase of efficiencies would be due to the promoted formation of photoactive α-formamidinium cesium lead triiodide perovskite crystals. |
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id | doaj-art-133528490dd74fd798f3ffd852a39a53 |
institution | Kabale University |
issn | 2304-6740 |
language | English |
publishDate | 2025-01-01 |
publisher | MDPI AG |
record_format | Article |
series | Inorganics |
spelling | doaj-art-133528490dd74fd798f3ffd852a39a532025-01-24T13:35:29ZengMDPI AGInorganics2304-67402025-01-011311510.3390/inorganics13010015Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium AdditionAyu Enomoto0Atsushi Suzuki1Takeo Oku2Haruto Shimada3Department of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanDepartment of Materials Chemistry, The University of Shiga Prefecture, 2500 Hassaka, Hikone 522-8533, Shiga, JapanGermanium (Ge) was added to formamidinium cesium lead triiodide perovskite crystals and the microstructures and photovoltaic properties were investigated. The Ge addition stabilized the α-phase of the perovskites and suppressed formation of the δ-phase. X-ray diffraction peaks of the α-phase increased by increasing the Ge contents. The highest conversion efficiency of 6.05% was obtained for the 12.5% Ge added device in an air atmosphere and the increase of efficiencies would be due to the promoted formation of photoactive α-formamidinium cesium lead triiodide perovskite crystals.https://www.mdpi.com/2304-6740/13/1/15perovskite solar cellgermaniumFAPbI<sub>3</sub>first principle calculation |
spellingShingle | Ayu Enomoto Atsushi Suzuki Takeo Oku Haruto Shimada Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition Inorganics perovskite solar cell germanium FAPbI<sub>3</sub> first principle calculation |
title | Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition |
title_full | Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition |
title_fullStr | Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition |
title_full_unstemmed | Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition |
title_short | Promoted Formation of Photoactive α-Formamidinium Cesium Lead Triiodide Perovskite Crystals by Germanium Addition |
title_sort | promoted formation of photoactive α formamidinium cesium lead triiodide perovskite crystals by germanium addition |
topic | perovskite solar cell germanium FAPbI<sub>3</sub> first principle calculation |
url | https://www.mdpi.com/2304-6740/13/1/15 |
work_keys_str_mv | AT ayuenomoto promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition AT atsushisuzuki promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition AT takeooku promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition AT harutoshimada promotedformationofphotoactiveaformamidiniumcesiumleadtriiodideperovskitecrystalsbygermaniumaddition |