Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina

The study describes the removal of fluoride from drinking water using modified immobilized activated alumina (MIAA) prepared by sol-gel method. The modification was done by adding a specific amount of alum during the sol formation step. The fluoride removal efficiency of MIAA was 1.35 times higher a...

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Main Authors: Aneeza Rafique, M. Ali Awan, Ayesha Wasti, Ishtiaq A. Qazi, Muhammad Arshad
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/386476
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author Aneeza Rafique
M. Ali Awan
Ayesha Wasti
Ishtiaq A. Qazi
Muhammad Arshad
author_facet Aneeza Rafique
M. Ali Awan
Ayesha Wasti
Ishtiaq A. Qazi
Muhammad Arshad
author_sort Aneeza Rafique
collection DOAJ
description The study describes the removal of fluoride from drinking water using modified immobilized activated alumina (MIAA) prepared by sol-gel method. The modification was done by adding a specific amount of alum during the sol formation step. The fluoride removal efficiency of MIAA was 1.35 times higher as compared to normal immobilized activated alumina. A batch adsorption study was performed as a function of adsorbent dose, contact time, stirring rate, and initial fluoride concentration. More than 90% removal of fluoride was achieved within 60 minutes of contact time. The adsorption potential of MIAA was compared with activated charcoal which showed that the removal efficiency was about 10% more than the activated charcoal. Both the Langmuir and Freundlich adsorption isotherms fitted well for the fluoride adsorption on MIAA with the regression coefficient R2 of 0.99 and 0.98, respectively. MIAA can both be regenerated thermally and chemically. Adsorption experiments using MIAA were employed on real drinking water samples from a fluoride affected area. The study showed that modified immobilized activated alumina is an effective adsorbent for fluoride removal.
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institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-1322bae05cfd45f6934f5f9bb495ac022025-02-03T06:10:48ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/386476386476Removal of Fluoride from Drinking Water Using Modified Immobilized Activated AluminaAneeza Rafique0M. Ali Awan1Ayesha Wasti2Ishtiaq A. Qazi3Muhammad Arshad4Institute of Environmental Science and Engineering, School of Civil and Environmental Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000, PakistanInstitute of Environmental Science and Engineering, School of Civil and Environmental Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000, PakistanInstitute of Environmental Science and Engineering, School of Civil and Environmental Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000, PakistanInstitute of Environmental Science and Engineering, School of Civil and Environmental Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000, PakistanInstitute of Environmental Science and Engineering, School of Civil and Environmental Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000, PakistanThe study describes the removal of fluoride from drinking water using modified immobilized activated alumina (MIAA) prepared by sol-gel method. The modification was done by adding a specific amount of alum during the sol formation step. The fluoride removal efficiency of MIAA was 1.35 times higher as compared to normal immobilized activated alumina. A batch adsorption study was performed as a function of adsorbent dose, contact time, stirring rate, and initial fluoride concentration. More than 90% removal of fluoride was achieved within 60 minutes of contact time. The adsorption potential of MIAA was compared with activated charcoal which showed that the removal efficiency was about 10% more than the activated charcoal. Both the Langmuir and Freundlich adsorption isotherms fitted well for the fluoride adsorption on MIAA with the regression coefficient R2 of 0.99 and 0.98, respectively. MIAA can both be regenerated thermally and chemically. Adsorption experiments using MIAA were employed on real drinking water samples from a fluoride affected area. The study showed that modified immobilized activated alumina is an effective adsorbent for fluoride removal.http://dx.doi.org/10.1155/2013/386476
spellingShingle Aneeza Rafique
M. Ali Awan
Ayesha Wasti
Ishtiaq A. Qazi
Muhammad Arshad
Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
Journal of Chemistry
title Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
title_full Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
title_fullStr Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
title_full_unstemmed Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
title_short Removal of Fluoride from Drinking Water Using Modified Immobilized Activated Alumina
title_sort removal of fluoride from drinking water using modified immobilized activated alumina
url http://dx.doi.org/10.1155/2013/386476
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AT ishtiaqaqazi removaloffluoridefromdrinkingwaterusingmodifiedimmobilizedactivatedalumina
AT muhammadarshad removaloffluoridefromdrinkingwaterusingmodifiedimmobilizedactivatedalumina