Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures
Mixing rules coupled to a semipredictive kinetic model of the Langmuir-Hinshelwood type were proposed to determine the behavior of the heterogeneous solar photodegradation with TiO2-P25 of multicomponent mixtures at pilot scale. The kinetic expressions were expressed in terms of the effective concen...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/2014/817538 |
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| author | John Wilman Rodriguez-Acosta Miguel Ángel Mueses Fiderman Machuca-Martínez |
| author_facet | John Wilman Rodriguez-Acosta Miguel Ángel Mueses Fiderman Machuca-Martínez |
| author_sort | John Wilman Rodriguez-Acosta |
| collection | DOAJ |
| description | Mixing rules coupled to a semipredictive kinetic model of the Langmuir-Hinshelwood type were proposed to determine the behavior of the heterogeneous solar photodegradation with TiO2-P25 of multicomponent mixtures at pilot scale. The kinetic expressions were expressed in terms of the effective concentration of total organic carbon (xTOC). An expression was obtained in a generalized form which is a function of the mixing rules as a product of a global contribution of the reaction rate constant k′ and a mixing function fC. Kinetic parameters of the model were obtained using the Nelder and Mead (N-M) algorithm. The kinetic model was validated with experimental data obtained from the degradation of binary mixtures of chlorinated compounds (DCA: dichloroacetic acid and 4-CP: 4-chlorophenol) at different initial global concentration, using a CPC reactor at pilot scale. A simplex-lattice {2,3} design experiment was adopted to perform the runs. |
| format | Article |
| id | doaj-art-125f4d60f9094a4f84edbe9934ee726c |
| institution | Kabale University |
| issn | 1110-662X 1687-529X |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj-art-125f4d60f9094a4f84edbe9934ee726c2025-02-03T01:10:15ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2014-01-01201410.1155/2014/817538817538Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent MixturesJohn Wilman Rodriguez-Acosta0Miguel Ángel Mueses1Fiderman Machuca-Martínez2Gaox Research Group, Chemical Engineering School, Universidad del Valle, A.A. 25360 Cali, ColombiaPhotocatalysis and Solar Photoreactors Engineering, Department of Chemical Engineering, Universidad de Cartagena, Postal 195, A.A. 1382 Cartagena, ColombiaGaox Research Group, Chemical Engineering School, Universidad del Valle, A.A. 25360 Cali, ColombiaMixing rules coupled to a semipredictive kinetic model of the Langmuir-Hinshelwood type were proposed to determine the behavior of the heterogeneous solar photodegradation with TiO2-P25 of multicomponent mixtures at pilot scale. The kinetic expressions were expressed in terms of the effective concentration of total organic carbon (xTOC). An expression was obtained in a generalized form which is a function of the mixing rules as a product of a global contribution of the reaction rate constant k′ and a mixing function fC. Kinetic parameters of the model were obtained using the Nelder and Mead (N-M) algorithm. The kinetic model was validated with experimental data obtained from the degradation of binary mixtures of chlorinated compounds (DCA: dichloroacetic acid and 4-CP: 4-chlorophenol) at different initial global concentration, using a CPC reactor at pilot scale. A simplex-lattice {2,3} design experiment was adopted to perform the runs.http://dx.doi.org/10.1155/2014/817538 |
| spellingShingle | John Wilman Rodriguez-Acosta Miguel Ángel Mueses Fiderman Machuca-Martínez Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures International Journal of Photoenergy |
| title | Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures |
| title_full | Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures |
| title_fullStr | Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures |
| title_full_unstemmed | Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures |
| title_short | Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures |
| title_sort | mixing rules formulation for a kinetic model of the langmuir hinshelwood semipredictive type applied to the heterogeneous photocatalytic degradation of multicomponent mixtures |
| url | http://dx.doi.org/10.1155/2014/817538 |
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