Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders

The interactions of copper substrate with titanium-alloyed Sn-Zn eutectic solders have been studied. Two series of experiments have been performed. The first one consisted in differential thermal analyses of Sn-Zn nearly eutectic alloys containing from 1.3 to 2.2 wt. % Ti. Diffusion couples consiste...

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Main Authors: Soares D., Barbosa J., Vilarinho C.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2006-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2006/1450-53390601045S.pdf
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author Soares D.
Barbosa J.
Vilarinho C.
author_facet Soares D.
Barbosa J.
Vilarinho C.
author_sort Soares D.
collection DOAJ
description The interactions of copper substrate with titanium-alloyed Sn-Zn eutectic solders have been studied. Two series of experiments have been performed. The first one consisted in differential thermal analyses of Sn-Zn nearly eutectic alloys containing from 1.3 to 2.2 wt. % Ti. Diffusion couples consisted of Cu-wires and Sn-Zn-Ti liquid solders, produced at 250 and 275 OC have been prepared in the second series,. The contact times were up to 3600 s. The contact zones have been characterized by optical and scanning electron microscope. Two layers have been found along the interfaces solid/liquid. The first and the second layers are identical, respectively, with γ and ε phases of the Cu-Zn system. No changes of the chemical compositions were detected for the tested temperatures and reaction times. Continuous parabolic growth of the total diffusion zone thickness with the time of diffusion is observed. The growth is due mainly to one the formed layers (γ ) while the thickness of the ε-phase layer, stays almost constant for all tested diffusion times and temperatures.
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record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-1161afcd54b042928eeae19a6d27212a2025-02-03T02:50:32ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392006-01-01421455610.2298/JMMB0601045SInteractions of Cu-substrates with titanium-alloyed Sn-Zn soldersSoares D.Barbosa J.Vilarinho C.The interactions of copper substrate with titanium-alloyed Sn-Zn eutectic solders have been studied. Two series of experiments have been performed. The first one consisted in differential thermal analyses of Sn-Zn nearly eutectic alloys containing from 1.3 to 2.2 wt. % Ti. Diffusion couples consisted of Cu-wires and Sn-Zn-Ti liquid solders, produced at 250 and 275 OC have been prepared in the second series,. The contact times were up to 3600 s. The contact zones have been characterized by optical and scanning electron microscope. Two layers have been found along the interfaces solid/liquid. The first and the second layers are identical, respectively, with γ and ε phases of the Cu-Zn system. No changes of the chemical compositions were detected for the tested temperatures and reaction times. Continuous parabolic growth of the total diffusion zone thickness with the time of diffusion is observed. The growth is due mainly to one the formed layers (γ ) while the thickness of the ε-phase layer, stays almost constant for all tested diffusion times and temperatures.http://www.doiserbia.nb.rs/img/doi/1450-5339/2006/1450-53390601045S.pdflead-free soldersdiffusion couplesCu/(Sn-Zn-Ti) interactions
spellingShingle Soares D.
Barbosa J.
Vilarinho C.
Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
Journal of Mining and Metallurgy. Section B: Metallurgy
lead-free solders
diffusion couples
Cu/(Sn-Zn-Ti) interactions
title Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
title_full Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
title_fullStr Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
title_full_unstemmed Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
title_short Interactions of Cu-substrates with titanium-alloyed Sn-Zn solders
title_sort interactions of cu substrates with titanium alloyed sn zn solders
topic lead-free solders
diffusion couples
Cu/(Sn-Zn-Ti) interactions
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2006/1450-53390601045S.pdf
work_keys_str_mv AT soaresd interactionsofcusubstrateswithtitaniumalloyedsnznsolders
AT barbosaj interactionsofcusubstrateswithtitaniumalloyedsnznsolders
AT vilarinhoc interactionsofcusubstrateswithtitaniumalloyedsnznsolders