Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III)
Skewered Iron(III) phthalocyanine conducting polymer can be constructed with the utilization of axial thiocyanato ligands ((μ-thiocyanato)(phthalocyaninato)iron(III)); (FeIII(Pc)(SCN)n) thereby creating additional avenues for electron transport through a linear SCN bridge, apart from the intermolecu...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | Journal of Nanotechnology |
| Online Access: | http://dx.doi.org/10.1155/2016/5175462 |
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| author | Eiza Shimizu Gil Nonato Santos Derrick Ethelbhert Yu |
| author_facet | Eiza Shimizu Gil Nonato Santos Derrick Ethelbhert Yu |
| author_sort | Eiza Shimizu |
| collection | DOAJ |
| description | Skewered Iron(III) phthalocyanine conducting polymer can be constructed with the utilization of axial thiocyanato ligands ((μ-thiocyanato)(phthalocyaninato)iron(III)); (FeIII(Pc)(SCN)n) thereby creating additional avenues for electron transport through a linear SCN bridge, apart from the intermolecular π-π orbital overlap between the Pc molecules. In this paper, we report on the conversion of bulk FeIII(Pc)(SCN)n polymeric organic conductor into crystalline nanostructures through horizontal vapor phase growth process. The needle-like nanostructures are deemed to provide more ordered and, thus, more π-π interactive interskewer FeIII(Pc)(SCN)n polymer orientation, resulting in a twofold increase of its electrical conductivity per materials density unit. |
| format | Article |
| id | doaj-art-0f7e2729cc4140a1890986ef269980df |
| institution | Kabale University |
| issn | 1687-9503 1687-9511 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Nanotechnology |
| spelling | doaj-art-0f7e2729cc4140a1890986ef269980df2025-02-03T01:22:16ZengWileyJournal of Nanotechnology1687-95031687-95112016-01-01201610.1155/2016/51754625175462Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III)Eiza Shimizu0Gil Nonato Santos1Derrick Ethelbhert Yu2Department of Chemistry, College of Science, De La Salle University, 2401 Taft Avenue, Manila, PhilippinesDepartment of Physics, College of Science, De La Salle University, 2401 Taft Avenue, Manila, PhilippinesDepartment of Chemistry, College of Science, De La Salle University, 2401 Taft Avenue, Manila, PhilippinesSkewered Iron(III) phthalocyanine conducting polymer can be constructed with the utilization of axial thiocyanato ligands ((μ-thiocyanato)(phthalocyaninato)iron(III)); (FeIII(Pc)(SCN)n) thereby creating additional avenues for electron transport through a linear SCN bridge, apart from the intermolecular π-π orbital overlap between the Pc molecules. In this paper, we report on the conversion of bulk FeIII(Pc)(SCN)n polymeric organic conductor into crystalline nanostructures through horizontal vapor phase growth process. The needle-like nanostructures are deemed to provide more ordered and, thus, more π-π interactive interskewer FeIII(Pc)(SCN)n polymer orientation, resulting in a twofold increase of its electrical conductivity per materials density unit.http://dx.doi.org/10.1155/2016/5175462 |
| spellingShingle | Eiza Shimizu Gil Nonato Santos Derrick Ethelbhert Yu Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) Journal of Nanotechnology |
| title | Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) |
| title_full | Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) |
| title_fullStr | Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) |
| title_full_unstemmed | Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) |
| title_short | Nanocrystalline Axially Bridged Iron Phthalocyanine Polymeric Conductor: (μ-Thiocyanato)(phthalocyaninato)iron(III) |
| title_sort | nanocrystalline axially bridged iron phthalocyanine polymeric conductor μ thiocyanato phthalocyaninato iron iii |
| url | http://dx.doi.org/10.1155/2016/5175462 |
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