Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model

The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory...

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Main Authors: Xing Hu, Hu Xu, Chenglin Ding, Yupeng Tian, Kuo Yang
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Batteries
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Online Access:https://www.mdpi.com/2313-0105/11/7/280
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author Xing Hu
Hu Xu
Chenglin Ding
Yupeng Tian
Kuo Yang
author_facet Xing Hu
Hu Xu
Chenglin Ding
Yupeng Tian
Kuo Yang
author_sort Xing Hu
collection DOAJ
description The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity.
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id doaj-art-0df435d45e6e4ed0a7e22b97733d2c9c
institution Kabale University
issn 2313-0105
language English
publishDate 2025-07-01
publisher MDPI AG
record_format Article
series Batteries
spelling doaj-art-0df435d45e6e4ed0a7e22b97733d2c9c2025-08-20T03:58:25ZengMDPI AGBatteries2313-01052025-07-0111728010.3390/batteries11070280Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling ModelXing Hu0Hu Xu1Chenglin Ding2Yupeng Tian3Kuo Yang4School of Aeronautics, Shanghai Dianji University, Shanghai 201306, ChinaMechanical College, Shanghai Dianji University, Shanghai 201306, ChinaSchool of Artificial Intelligence, Shanghai Normal University Tianhua College, Shanghai 201815, ChinaMechanical College, Shanghai Dianji University, Shanghai 201306, ChinaMechanical College, Shanghai Dianji University, Shanghai 201306, ChinaThe escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity.https://www.mdpi.com/2313-0105/11/7/280lithium-ion batterieselectrochemical–thermal coupled modelhigh-rate dischargethermal safety
spellingShingle Xing Hu
Hu Xu
Chenglin Ding
Yupeng Tian
Kuo Yang
Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
Batteries
lithium-ion batteries
electrochemical–thermal coupled model
high-rate discharge
thermal safety
title Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
title_full Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
title_fullStr Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
title_full_unstemmed Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
title_short Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
title_sort numerical study on the thermal behavior of lithium ion batteries based on an electrochemical thermal coupling model
topic lithium-ion batteries
electrochemical–thermal coupled model
high-rate discharge
thermal safety
url https://www.mdpi.com/2313-0105/11/7/280
work_keys_str_mv AT xinghu numericalstudyonthethermalbehavioroflithiumionbatteriesbasedonanelectrochemicalthermalcouplingmodel
AT huxu numericalstudyonthethermalbehavioroflithiumionbatteriesbasedonanelectrochemicalthermalcouplingmodel
AT chenglinding numericalstudyonthethermalbehavioroflithiumionbatteriesbasedonanelectrochemicalthermalcouplingmodel
AT yupengtian numericalstudyonthethermalbehavioroflithiumionbatteriesbasedonanelectrochemicalthermalcouplingmodel
AT kuoyang numericalstudyonthethermalbehavioroflithiumionbatteriesbasedonanelectrochemicalthermalcouplingmodel