Use of Carbon Fibre Composite Molecular Sieves for Air Separation

The adsorption of oxygen, nitrogen and carbon dioxide onto a carbon fibre composite was investigated using static and dynamic techniques. Molecular-sieving effects in the composite were highlighted by the adsorption of carbon dioxide, a more sensitive probe molecule for the presence of micro-porosit...

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Main Authors: Timothy D. Burchell, Omats O. Omatete, Nidia C. Gallego, Frederick S. Baker
Format: Article
Language:English
Published: SAGE Publishing 2005-04-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263617054353618
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author Timothy D. Burchell
Omats O. Omatete
Nidia C. Gallego
Frederick S. Baker
author_facet Timothy D. Burchell
Omats O. Omatete
Nidia C. Gallego
Frederick S. Baker
author_sort Timothy D. Burchell
collection DOAJ
description The adsorption of oxygen, nitrogen and carbon dioxide onto a carbon fibre composite was investigated using static and dynamic techniques. Molecular-sieving effects in the composite were highlighted by the adsorption of carbon dioxide, a more sensitive probe molecule for the presence of micro-porosity in adsorbents. The kinetic studies revealed that oxygen was more rapidly adsorbed on the composite than nitrogen and with a higher uptake under equilibrium conditions. Preliminary experiments indicated that the carbon fibre composite was capable of separating oxygen and nitrogen from air on the basis of the different diffusion rates of the two molecules in the micropore network of the composite. It is proposed that the relatively high electrical conductivity of the carbon fibre composite material could be exploited for air separation by facilitating the production of O 2 and N 2 through electrical swing adsorption rather than the depressurization of adsorber beds.
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institution Kabale University
issn 0263-6174
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publishDate 2005-04-01
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series Adsorption Science & Technology
spelling doaj-art-0c0346ebee404b6491f9f6193ad0cf402025-02-03T10:07:34ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382005-04-012310.1260/0263617054353618Use of Carbon Fibre Composite Molecular Sieves for Air SeparationTimothy D. BurchellOmats O. OmateteNidia C. GallegoFrederick S. BakerThe adsorption of oxygen, nitrogen and carbon dioxide onto a carbon fibre composite was investigated using static and dynamic techniques. Molecular-sieving effects in the composite were highlighted by the adsorption of carbon dioxide, a more sensitive probe molecule for the presence of micro-porosity in adsorbents. The kinetic studies revealed that oxygen was more rapidly adsorbed on the composite than nitrogen and with a higher uptake under equilibrium conditions. Preliminary experiments indicated that the carbon fibre composite was capable of separating oxygen and nitrogen from air on the basis of the different diffusion rates of the two molecules in the micropore network of the composite. It is proposed that the relatively high electrical conductivity of the carbon fibre composite material could be exploited for air separation by facilitating the production of O 2 and N 2 through electrical swing adsorption rather than the depressurization of adsorber beds.https://doi.org/10.1260/0263617054353618
spellingShingle Timothy D. Burchell
Omats O. Omatete
Nidia C. Gallego
Frederick S. Baker
Use of Carbon Fibre Composite Molecular Sieves for Air Separation
Adsorption Science & Technology
title Use of Carbon Fibre Composite Molecular Sieves for Air Separation
title_full Use of Carbon Fibre Composite Molecular Sieves for Air Separation
title_fullStr Use of Carbon Fibre Composite Molecular Sieves for Air Separation
title_full_unstemmed Use of Carbon Fibre Composite Molecular Sieves for Air Separation
title_short Use of Carbon Fibre Composite Molecular Sieves for Air Separation
title_sort use of carbon fibre composite molecular sieves for air separation
url https://doi.org/10.1260/0263617054353618
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AT omatsoomatete useofcarbonfibrecompositemolecularsievesforairseparation
AT nidiacgallego useofcarbonfibrecompositemolecularsievesforairseparation
AT fredericksbaker useofcarbonfibrecompositemolecularsievesforairseparation