Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications
Abstract Exploring ionogels with superior conductivity, mechanical properties, and long‐lasting room temperature phosphorescence (RTP) offers considerable potential for new‐generation optoelectronics. However, reports on ionogels remain limited owing to the contradiction between the flexibility requ...
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Wiley
2025-02-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202411229 |
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| author | Xuefeng Wei Zexi Gou Jianting Ye L. H. Shi Jianwei Zhao Lei Yang Linbo Zhang Kun Zhang Ruonan Jia |
| author_facet | Xuefeng Wei Zexi Gou Jianting Ye L. H. Shi Jianwei Zhao Lei Yang Linbo Zhang Kun Zhang Ruonan Jia |
| author_sort | Xuefeng Wei |
| collection | DOAJ |
| description | Abstract Exploring ionogels with superior conductivity, mechanical properties, and long‐lasting room temperature phosphorescence (RTP) offers considerable potential for new‐generation optoelectronics. However, reports on ionogels remain limited owing to the contradiction between the flexibility required for stretching and the rigidity necessary for RTP and load‐bearing within the same ionogels. Here, a facile strategy is reported to enhance the toughness and extend the RTP of ionogels by salting‐out‐induced microphase separation, which results in the formation of an IL‐rich phase (soft) for stretching and ionic conduction and a polymer‐rich phase (stiff) for energy dissipation and clustering‐triggered phosphorescence. The obtained ionogels exhibit high stretchability (≈400% strain), toughness (≈∼20 MJ m−3), ionic conductivity (8.4 mS cm−1), and ultralong afterglow lifetime (112.4 ms). This strategy is applicable to chromophores with color‐tunable phosphorescence. By leveraging observable full‐color RTP and real‐time electrical signals in response to diverse stimuli (i.e., stretching and pressing), an intelligent grasping strategy is developed for robust hand pose reconstruction. In addition, a tactile‐visual fusion recognition keyboard is created with dual functionality of information encryption and signal transmission. The ease of fabrication, wide tunability, and multifunctionality will help expand the scope of ionogels for smart devices. |
| format | Article |
| id | doaj-art-0b91b7593a024159935d4827b60884d6 |
| institution | Kabale University |
| issn | 2198-3844 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Wiley |
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| series | Advanced Science |
| spelling | doaj-art-0b91b7593a024159935d4827b60884d62025-02-04T13:14:54ZengWileyAdvanced Science2198-38442025-02-01125n/an/a10.1002/advs.202411229Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration ApplicationsXuefeng Wei0Zexi Gou1Jianting Ye2L. H. Shi3Jianwei Zhao4Lei Yang5Linbo Zhang6Kun Zhang7Ruonan Jia8Sichuan Provincial People's Hospital School of Medicine University of Electronic Science and Technology of China Chengdu 610072 ChinaNational Engineering Research Center of Electromagnetic Radiation Control Materials Key Laboratory of Multi‐spectral Absorbing Materials and Structures of Ministry of Education University of Electronic Science and Technology of China Chengdu 610072 ChinaCollege of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu 610059 ChinaCollege of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu 610059 ChinaShenzhen HUASUAN Technology Co., Ltd. Shenzhen 518107 ChinaShenzhen HUASUAN Technology Co., Ltd. Shenzhen 518107 ChinaNational Engineering Research Center of Electromagnetic Radiation Control Materials Key Laboratory of Multi‐spectral Absorbing Materials and Structures of Ministry of Education University of Electronic Science and Technology of China Chengdu 610072 ChinaSichuan Provincial People's Hospital School of Medicine University of Electronic Science and Technology of China Chengdu 610072 ChinaSichuan Provincial People's Hospital School of Medicine University of Electronic Science and Technology of China Chengdu 610072 ChinaAbstract Exploring ionogels with superior conductivity, mechanical properties, and long‐lasting room temperature phosphorescence (RTP) offers considerable potential for new‐generation optoelectronics. However, reports on ionogels remain limited owing to the contradiction between the flexibility required for stretching and the rigidity necessary for RTP and load‐bearing within the same ionogels. Here, a facile strategy is reported to enhance the toughness and extend the RTP of ionogels by salting‐out‐induced microphase separation, which results in the formation of an IL‐rich phase (soft) for stretching and ionic conduction and a polymer‐rich phase (stiff) for energy dissipation and clustering‐triggered phosphorescence. The obtained ionogels exhibit high stretchability (≈400% strain), toughness (≈∼20 MJ m−3), ionic conductivity (8.4 mS cm−1), and ultralong afterglow lifetime (112.4 ms). This strategy is applicable to chromophores with color‐tunable phosphorescence. By leveraging observable full‐color RTP and real‐time electrical signals in response to diverse stimuli (i.e., stretching and pressing), an intelligent grasping strategy is developed for robust hand pose reconstruction. In addition, a tactile‐visual fusion recognition keyboard is created with dual functionality of information encryption and signal transmission. The ease of fabrication, wide tunability, and multifunctionality will help expand the scope of ionogels for smart devices.https://doi.org/10.1002/advs.202411229ionogelsoptoelectronicsphosphorescencePVAstretchable |
| spellingShingle | Xuefeng Wei Zexi Gou Jianting Ye L. H. Shi Jianwei Zhao Lei Yang Linbo Zhang Kun Zhang Ruonan Jia Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications Advanced Science ionogels optoelectronics phosphorescence PVA stretchable |
| title | Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications |
| title_full | Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications |
| title_fullStr | Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications |
| title_full_unstemmed | Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications |
| title_short | Stretchable Full‐Color Phosphorescent PVA‐Based Ionogels for Multimodal Sensing‐Visual Integration Applications |
| title_sort | stretchable full color phosphorescent pva based ionogels for multimodal sensing visual integration applications |
| topic | ionogels optoelectronics phosphorescence PVA stretchable |
| url | https://doi.org/10.1002/advs.202411229 |
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