Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process

Nanostructures of noble metals (Pt and Ag) on carbon support were prepared from fructose and solution of the Nobel metal salts (H2PtCl6 x 6H2O or AgNO3) under hydrothermal conditions. Commercial fructose (C6H12O6) acts as the carbon source and reducing agent and noble metal salts is a source of the...

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Main Authors: Sanja Krstić, Vladislava M. Jovanović
Format: Article
Language:English
Published: Engineering Society for Corrosion, Belgrade 2015-12-01
Series:Zaštita Materijala
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Online Access:https://www.zastita-materijala.org/index.php/home/article/view/757
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author Sanja Krstić
Vladislava M. Jovanović
author_facet Sanja Krstić
Vladislava M. Jovanović
author_sort Sanja Krstić
collection DOAJ
description Nanostructures of noble metals (Pt and Ag) on carbon support were prepared from fructose and solution of the Nobel metal salts (H2PtCl6 x 6H2O or AgNO3) under hydrothermal conditions. Commercial fructose (C6H12O6) acts as the carbon source and reducing agent and noble metal salts is a source of the metal to be incorporated in the new formed carbon material structure. The crystalline structure was examined by X-ray diffraction (XRD) and morphology investigated by scanning electron microscopy (SEM). The crystallite size of the deposited particles could be estimated by evaluating the line width of the Bragg peak applying the Scherrer method. All the XRD patterns clearly show the five main characteristic peaks of the face-centered cubic (fcc) crystalline for both Pt and Ag crystallite. The obtained Pt crystallite sizes were below 5.5 nm, while the Ag crystallite sizes were about 32 or 34nm.
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language English
publishDate 2015-12-01
publisher Engineering Society for Corrosion, Belgrade
record_format Article
series Zaštita Materijala
spelling doaj-art-0a931a0478ab4fcaade9c80abc4f62b32025-08-20T03:55:27ZengEngineering Society for Corrosion, BelgradeZaštita Materijala0351-94652466-25852015-12-0156440941210.5937/ZasMat1504409K756Direct synthesis of noble metal nanostructures on carbon support by hydrothermal processSanja Krstić0Vladislava M. Jovanović1University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča, SerbiaUniversity of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM, SerbiaNanostructures of noble metals (Pt and Ag) on carbon support were prepared from fructose and solution of the Nobel metal salts (H2PtCl6 x 6H2O or AgNO3) under hydrothermal conditions. Commercial fructose (C6H12O6) acts as the carbon source and reducing agent and noble metal salts is a source of the metal to be incorporated in the new formed carbon material structure. The crystalline structure was examined by X-ray diffraction (XRD) and morphology investigated by scanning electron microscopy (SEM). The crystallite size of the deposited particles could be estimated by evaluating the line width of the Bragg peak applying the Scherrer method. All the XRD patterns clearly show the five main characteristic peaks of the face-centered cubic (fcc) crystalline for both Pt and Ag crystallite. The obtained Pt crystallite sizes were below 5.5 nm, while the Ag crystallite sizes were about 32 or 34nm.https://www.zastita-materijala.org/index.php/home/article/view/757hydrothermal processplatinumsilvernanostructurecrystallite size
spellingShingle Sanja Krstić
Vladislava M. Jovanović
Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
Zaštita Materijala
hydrothermal process
platinum
silver
nanostructure
crystallite size
title Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
title_full Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
title_fullStr Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
title_full_unstemmed Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
title_short Direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
title_sort direct synthesis of noble metal nanostructures on carbon support by hydrothermal process
topic hydrothermal process
platinum
silver
nanostructure
crystallite size
url https://www.zastita-materijala.org/index.php/home/article/view/757
work_keys_str_mv AT sanjakrstic directsynthesisofnoblemetalnanostructuresoncarbonsupportbyhydrothermalprocess
AT vladislavamjovanovic directsynthesisofnoblemetalnanostructuresoncarbonsupportbyhydrothermalprocess