Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound

New inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (...

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Main Authors: A. Oueslati, I. Chaabane, K. Adil, F. Hlel
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/435462
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author A. Oueslati
I. Chaabane
K. Adil
F. Hlel
author_facet A. Oueslati
I. Chaabane
K. Adil
F. Hlel
author_sort A. Oueslati
collection DOAJ
description New inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (2). Besides, its structure was solved using 84860 independent reflections leading to . Electrical properties of the material were studied using impedance spectroscopic technique at different temperatures in the frequency range of 209 Hz to 5 MHz. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature-dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound.
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institution Kabale University
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series Journal of Chemistry
spelling doaj-art-0a38f90b2499486f94746e005c8d27ab2025-02-03T01:12:10ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/435462435462Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid CompoundA. Oueslati0I. Chaabane1K. Adil2F. Hlel3Laboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaLaboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaLaboratoire des Oxydes et Fluorures, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 05, FranceLaboratoire de l'État Solide, Faculté des Sciences de Sfax, Université de Sfax, 3000 Sfax, TunisiaNew inorganic-organic hybrid [(C3H7)4N]2Hg2Cl6 compound was obtained and characterised by single-crystal X-ray diffraction, infrared, and impedance spectroscopy. The latter crystallizes in the monoclinic system (space group C 2/c, ) with the following unit cell dimensions: (1) Å, (6) Å, (2) Å, and (2). Besides, its structure was solved using 84860 independent reflections leading to . Electrical properties of the material were studied using impedance spectroscopic technique at different temperatures in the frequency range of 209 Hz to 5 MHz. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature-dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound.http://dx.doi.org/10.1155/2013/435462
spellingShingle A. Oueslati
I. Chaabane
K. Adil
F. Hlel
Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
Journal of Chemistry
title Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
title_full Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
title_fullStr Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
title_full_unstemmed Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
title_short Structural Characterization and Infrared and Electrical Properties of the New Inorganic-Organic Hybrid Compound
title_sort structural characterization and infrared and electrical properties of the new inorganic organic hybrid compound
url http://dx.doi.org/10.1155/2013/435462
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