New Type of Donor-Acceptor Through-Space Conjugated Polymer
We report the synthesis and properties of a novel through-space conjugated polymer with a [2.2]paracyclophane skeleton. The obtained polymer possessed donor (fluorene) and acceptor (2,1,3-benzothiadiazole) segments that were alternately π-stacked in proximity via the [2.2]paracyclophane moieties. Th...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2010/908128 |
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| _version_ | 1832558011162296320 |
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| author | Lin Lin Yasuhiro Morisaki Yoshiki Chujo |
| author_facet | Lin Lin Yasuhiro Morisaki Yoshiki Chujo |
| author_sort | Lin Lin |
| collection | DOAJ |
| description | We report the synthesis and properties of a novel through-space conjugated polymer with a [2.2]paracyclophane skeleton. The obtained polymer possessed donor (fluorene) and acceptor (2,1,3-benzothiadiazole) segments that were alternately π-stacked in proximity via the [2.2]paracyclophane moieties. The good overlap between the emission peak of the donor unit (fluorene) and the CT band of the acceptor unit (2,1,3-benzothiadiazole) caused fluorescence resonance energy transfer, and the visible green light emission from the acceptor unit was observed. |
| format | Article |
| id | doaj-art-0a223c9b12f041d48023c0da229c02af |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-0a223c9b12f041d48023c0da229c02af2025-02-03T01:33:26ZengWileyInternational Journal of Polymer Science1687-94221687-94302010-01-01201010.1155/2010/908128908128New Type of Donor-Acceptor Through-Space Conjugated PolymerLin Lin0Yasuhiro Morisaki1Yoshiki Chujo2Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, JapanDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, JapanDepartment of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, JapanWe report the synthesis and properties of a novel through-space conjugated polymer with a [2.2]paracyclophane skeleton. The obtained polymer possessed donor (fluorene) and acceptor (2,1,3-benzothiadiazole) segments that were alternately π-stacked in proximity via the [2.2]paracyclophane moieties. The good overlap between the emission peak of the donor unit (fluorene) and the CT band of the acceptor unit (2,1,3-benzothiadiazole) caused fluorescence resonance energy transfer, and the visible green light emission from the acceptor unit was observed.http://dx.doi.org/10.1155/2010/908128 |
| spellingShingle | Lin Lin Yasuhiro Morisaki Yoshiki Chujo New Type of Donor-Acceptor Through-Space Conjugated Polymer International Journal of Polymer Science |
| title | New Type of Donor-Acceptor Through-Space Conjugated Polymer |
| title_full | New Type of Donor-Acceptor Through-Space Conjugated Polymer |
| title_fullStr | New Type of Donor-Acceptor Through-Space Conjugated Polymer |
| title_full_unstemmed | New Type of Donor-Acceptor Through-Space Conjugated Polymer |
| title_short | New Type of Donor-Acceptor Through-Space Conjugated Polymer |
| title_sort | new type of donor acceptor through space conjugated polymer |
| url | http://dx.doi.org/10.1155/2010/908128 |
| work_keys_str_mv | AT linlin newtypeofdonoracceptorthroughspaceconjugatedpolymer AT yasuhiromorisaki newtypeofdonoracceptorthroughspaceconjugatedpolymer AT yoshikichujo newtypeofdonoracceptorthroughspaceconjugatedpolymer |