New Type of Donor-Acceptor Through-Space Conjugated Polymer
We report the synthesis and properties of a novel through-space conjugated polymer with a [2.2]paracyclophane skeleton. The obtained polymer possessed donor (fluorene) and acceptor (2,1,3-benzothiadiazole) segments that were alternately π-stacked in proximity via the [2.2]paracyclophane moieties. Th...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2010/908128 |
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| Summary: | We report the synthesis and properties of a novel through-space conjugated polymer with a [2.2]paracyclophane skeleton. The obtained polymer possessed donor (fluorene) and acceptor (2,1,3-benzothiadiazole) segments that were alternately π-stacked in proximity via the [2.2]paracyclophane moieties. The good overlap between the emission peak of the donor unit (fluorene) and the CT band of the acceptor unit (2,1,3-benzothiadiazole) caused fluorescence resonance energy transfer, and the visible green light emission from the acceptor unit was observed. |
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| ISSN: | 1687-9422 1687-9430 |