The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study
The oxidation of 2-(2-methoxyethoxy)ethanol (MEE) and 2-(2-ethoxyethoxy)ethanol (EEE) by ditelluratocuprate(III) (DTC) had been studied spectrophotometrically in alkaline medium. The reaction between and showed first-order dependence in DTC and fractional order in MEE and EEE. The rate constant o...
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2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/627324 |
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| author | Jin-huan Shan Yi Li Shu-ying Huo Cai-hong Yin |
| author_facet | Jin-huan Shan Yi Li Shu-ying Huo Cai-hong Yin |
| author_sort | Jin-huan Shan |
| collection | DOAJ |
| description | The oxidation of 2-(2-methoxyethoxy)ethanol (MEE) and 2-(2-ethoxyethoxy)ethanol (EEE) by ditelluratocuprate(III) (DTC) had been studied spectrophotometrically in alkaline medium. The reaction between and showed first-order dependence in DTC and fractional order in MEE and EEE. The rate constant of the pseudo-first-order reaction decreased with an increase of [TeO4 2−], whereas adding [OH−] enhanced the constant. In addition, the reaction had a negative salt effect. The rate of EEE was higher than that of MEE. A suitable assumption involving preequilibriums before the rate-controlling step and a free radical mechanism was proposed, based on the kinetic data. Activation parameters and the rate constant of the rate-determining step were calculated. |
| format | Article |
| id | doaj-art-09d72ad914d049b5b88329b06342266b |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-09d72ad914d049b5b88329b06342266b2025-02-03T01:02:51ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/627324627324The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic StudyJin-huan Shan0Yi Li1Shu-ying Huo2Cai-hong Yin3College of Chemistry and Environmental Science, Hebei University, Baoding, Hebei 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, Hebei 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, Hebei 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, Hebei 071002, ChinaThe oxidation of 2-(2-methoxyethoxy)ethanol (MEE) and 2-(2-ethoxyethoxy)ethanol (EEE) by ditelluratocuprate(III) (DTC) had been studied spectrophotometrically in alkaline medium. The reaction between and showed first-order dependence in DTC and fractional order in MEE and EEE. The rate constant of the pseudo-first-order reaction decreased with an increase of [TeO4 2−], whereas adding [OH−] enhanced the constant. In addition, the reaction had a negative salt effect. The rate of EEE was higher than that of MEE. A suitable assumption involving preequilibriums before the rate-controlling step and a free radical mechanism was proposed, based on the kinetic data. Activation parameters and the rate constant of the rate-determining step were calculated.http://dx.doi.org/10.1155/2013/627324 |
| spellingShingle | Jin-huan Shan Yi Li Shu-ying Huo Cai-hong Yin The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study Journal of Chemistry |
| title | The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study |
| title_full | The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study |
| title_fullStr | The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study |
| title_full_unstemmed | The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study |
| title_short | The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study |
| title_sort | oxidation of 2 2 methoxyethoxy ethanol and 2 2 ethoxyethoxy ethanol by ditelluratocuprate iii a kinetic and mechanistic study |
| url | http://dx.doi.org/10.1155/2013/627324 |
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