Recent research on chemically modifying the surface of zero-valent iron: A mini review

Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification invol...

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Main Authors: Zhendong Li, Wei Ye, Huiting Li, Jianzhe Qiao, Yunyi Du, Zhujun Dong, Lichun Fu, Yuwei Pan
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Chemical Engineering Journal Advances
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666821125000067
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author Zhendong Li
Wei Ye
Huiting Li
Jianzhe Qiao
Yunyi Du
Zhujun Dong
Lichun Fu
Yuwei Pan
author_facet Zhendong Li
Wei Ye
Huiting Li
Jianzhe Qiao
Yunyi Du
Zhujun Dong
Lichun Fu
Yuwei Pan
author_sort Zhendong Li
collection DOAJ
description Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification involves introducing specific chemical functional groups onto the surface of ZVI, altering its surface chemical properties and structural morphology. This article provides an overview of the advancements made in four commonly used chemical modifications of ZVI, namely ZVI sulfide, ZVI silicide, ZVI oxalate, and ZVI phosphate. The review examines the impacts of these four different modified compounds on the surface structure and reactivity of ZVI, as well as elucidates the mechanisms by which modified ZVI interacts with and removes pollutants. Furthermore, the article discusses the prospects and challenges associated with modified ZVI, offering valuable insights for future research and the application of environmental remediation technologies.
format Article
id doaj-art-0923ed316aa44587888dd9f1fbf9329d
institution Kabale University
issn 2666-8211
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Chemical Engineering Journal Advances
spelling doaj-art-0923ed316aa44587888dd9f1fbf9329d2025-02-03T04:17:05ZengElsevierChemical Engineering Journal Advances2666-82112025-03-0121100709Recent research on chemically modifying the surface of zero-valent iron: A mini reviewZhendong Li0Wei Ye1Huiting Li2Jianzhe Qiao3Yunyi Du4Zhujun Dong5Lichun Fu6Yuwei Pan7Laboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaLaboratory of Environmental Protection in Water Transport Engineering, Tianjin Research Institute of Water Transport Engineering, Tanggu, Tianjin 300456, ChinaCollege of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China; Corresponding authors.School of Iron and Steel, Soochow University, Suzhou 215000, ChinaCollege of Biology and the Environment, Nanjing Forestry University, Nanjing 210037, China; Corresponding authors.Zero-valent iron (ZVI) is a widely employed material for environmental remediation due to its capability to effectively degrade or reduce various pollutants. The enhancement of its reactivity and applicability can be achieved through chemical surface modification. Chemical surface modification involves introducing specific chemical functional groups onto the surface of ZVI, altering its surface chemical properties and structural morphology. This article provides an overview of the advancements made in four commonly used chemical modifications of ZVI, namely ZVI sulfide, ZVI silicide, ZVI oxalate, and ZVI phosphate. The review examines the impacts of these four different modified compounds on the surface structure and reactivity of ZVI, as well as elucidates the mechanisms by which modified ZVI interacts with and removes pollutants. Furthermore, the article discusses the prospects and challenges associated with modified ZVI, offering valuable insights for future research and the application of environmental remediation technologies.http://www.sciencedirect.com/science/article/pii/S2666821125000067Advances in ZVI surface chemistryZVI reactivity enhancementEnvironmental remediation with modified ZVIAdvanced oxidation processes
spellingShingle Zhendong Li
Wei Ye
Huiting Li
Jianzhe Qiao
Yunyi Du
Zhujun Dong
Lichun Fu
Yuwei Pan
Recent research on chemically modifying the surface of zero-valent iron: A mini review
Chemical Engineering Journal Advances
Advances in ZVI surface chemistry
ZVI reactivity enhancement
Environmental remediation with modified ZVI
Advanced oxidation processes
title Recent research on chemically modifying the surface of zero-valent iron: A mini review
title_full Recent research on chemically modifying the surface of zero-valent iron: A mini review
title_fullStr Recent research on chemically modifying the surface of zero-valent iron: A mini review
title_full_unstemmed Recent research on chemically modifying the surface of zero-valent iron: A mini review
title_short Recent research on chemically modifying the surface of zero-valent iron: A mini review
title_sort recent research on chemically modifying the surface of zero valent iron a mini review
topic Advances in ZVI surface chemistry
ZVI reactivity enhancement
Environmental remediation with modified ZVI
Advanced oxidation processes
url http://www.sciencedirect.com/science/article/pii/S2666821125000067
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