Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes
Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been eluci...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | Advances in Condensed Matter Physics |
| Online Access: | http://dx.doi.org/10.1155/2015/205047 |
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| author | João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva |
| author_facet | João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva |
| author_sort | João P. Martins |
| collection | DOAJ |
| description | Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations. |
| format | Article |
| id | doaj-art-08977fd5bfb6430584816cf8e3a47753 |
| institution | Kabale University |
| issn | 1687-8108 1687-8124 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Condensed Matter Physics |
| spelling | doaj-art-08977fd5bfb6430584816cf8e3a477532025-02-03T06:07:25ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242015-01-01201510.1155/2015/205047205047Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate ComplexesJoão P. Martins0Pablo Martín-Ramos1Pedro Chamorro-Posada2Pedro S. Pereira Silva3Jesús Martín-Gil4Salvador Hernández-Navarro5Manuela Ramos Silva6CFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalSignal Theory, Communications and Telematics Engineering Department, ETSIT, University of Valladolid, Campus Miguel Delibes, Paseo Belén 15, 47011 Valladolid, SpainCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalAdvanced Materials Laboratory, ETSIIAA, University of Valladolid, Avenida de Madrid 44, 34004 Palencia, SpainAdvanced Materials Laboratory, ETSIIAA, University of Valladolid, Avenida de Madrid 44, 34004 Palencia, SpainCFisUC, Department of Physics, University of Coimbra, Rua Larga, 3004-516 Coimbra, PortugalTwo novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.http://dx.doi.org/10.1155/2015/205047 |
| spellingShingle | João P. Martins Pablo Martín-Ramos Pedro Chamorro-Posada Pedro S. Pereira Silva Jesús Martín-Gil Salvador Hernández-Navarro Manuela Ramos Silva Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes Advances in Condensed Matter Physics |
| title | Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes |
| title_full | Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes |
| title_fullStr | Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes |
| title_full_unstemmed | Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes |
| title_short | Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) β-Diketonate Complexes |
| title_sort | experimental and theoretical studies on the structure and photoluminescent properties of new mononuclear and homodinuclear europium iii β diketonate complexes |
| url | http://dx.doi.org/10.1155/2015/205047 |
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