Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber

Evaluated removal of reactive orange 16 (RO16) dye from aqueous solution was studied in batch mode by using kenaf core fiber as low-cost adsorbents. In this attempt, kenaf core fiber with size 0.25–1 mm was treated by using (3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHMAC) as quaternizat...

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Main Authors: Maytham Kadhim Obaid, Luqman Chuah Abdullah, Intidhar Jabir Idan
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2016/4262578
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author Maytham Kadhim Obaid
Luqman Chuah Abdullah
Intidhar Jabir Idan
author_facet Maytham Kadhim Obaid
Luqman Chuah Abdullah
Intidhar Jabir Idan
author_sort Maytham Kadhim Obaid
collection DOAJ
description Evaluated removal of reactive orange 16 (RO16) dye from aqueous solution was studied in batch mode by using kenaf core fiber as low-cost adsorbents. In this attempt, kenaf core fiber with size 0.25–1 mm was treated by using (3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHMAC) as quaternization agent. Then effective parameters include adsorbent dose, pH, and contact time and initial dye concentration on adsorption by modified kenaf core fiber was investigated. In addition, isotherms and kinetics adsorption studies were estimated for determination of the equilibrium adsorption capacity and reactions dynamics, respectively. Results showed that the best dose of MKCF was 0.1 g/100 mL, the maximum removal of RO16 was 97.25 at 30°C, pH = 6.5, and agitation speed was 150 rpm. The results also showed that the equilibrium data were represented by Freundlich isotherm with correlation coefficients R2=0.9924, and the kinetic study followed the pseudo-second-order kinetic model with correlation coefficients R2=0.9997 for Co=100 mg/L. Furthermore, the maximum adsorption capacity was 416.86 mg/g. Adsorption through kenaf was found to be very effective for the removal of the RO16 dye.
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institution Kabale University
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spelling doaj-art-079f9e6b6a8d4506a895b152c939e1232025-02-03T01:27:14ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/42625784262578Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core FiberMaytham Kadhim Obaid0Luqman Chuah Abdullah1Intidhar Jabir Idan2Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor, MalaysiaDepartment of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor, MalaysiaEvaluated removal of reactive orange 16 (RO16) dye from aqueous solution was studied in batch mode by using kenaf core fiber as low-cost adsorbents. In this attempt, kenaf core fiber with size 0.25–1 mm was treated by using (3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHMAC) as quaternization agent. Then effective parameters include adsorbent dose, pH, and contact time and initial dye concentration on adsorption by modified kenaf core fiber was investigated. In addition, isotherms and kinetics adsorption studies were estimated for determination of the equilibrium adsorption capacity and reactions dynamics, respectively. Results showed that the best dose of MKCF was 0.1 g/100 mL, the maximum removal of RO16 was 97.25 at 30°C, pH = 6.5, and agitation speed was 150 rpm. The results also showed that the equilibrium data were represented by Freundlich isotherm with correlation coefficients R2=0.9924, and the kinetic study followed the pseudo-second-order kinetic model with correlation coefficients R2=0.9997 for Co=100 mg/L. Furthermore, the maximum adsorption capacity was 416.86 mg/g. Adsorption through kenaf was found to be very effective for the removal of the RO16 dye.http://dx.doi.org/10.1155/2016/4262578
spellingShingle Maytham Kadhim Obaid
Luqman Chuah Abdullah
Intidhar Jabir Idan
Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
Journal of Chemistry
title Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
title_full Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
title_fullStr Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
title_full_unstemmed Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
title_short Removal of Reactive Orange 16 Dye from Aqueous Solution by Using Modified Kenaf Core Fiber
title_sort removal of reactive orange 16 dye from aqueous solution by using modified kenaf core fiber
url http://dx.doi.org/10.1155/2016/4262578
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AT luqmanchuahabdullah removalofreactiveorange16dyefromaqueoussolutionbyusingmodifiedkenafcorefiber
AT intidharjabiridan removalofreactiveorange16dyefromaqueoussolutionbyusingmodifiedkenafcorefiber