Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant

In the paper, the physical and chemical characteristics of sulfur cake from Stepnogorsk Sulfuric Acid Plant (SSAP LLP) were studied. During the production of sulfuric acid, 130–200 tons of sulfur-containing residues are accumulated per year, the storage of which negatively affects the environment....

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Main Authors: Ye. Tileuberdi, Ye. Imanbayev, Ye. Kanzharkan, A. Kidyrali, S. Frolov, N. Bektenov
Format: Article
Language:English
Published: al-Farabi Kazakh National University 2024-12-01
Series:Eurasian Chemico-Technological Journal
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Online Access:https://ect-journal.kz/index.php/ectj/article/view/1661
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author Ye. Tileuberdi
Ye. Imanbayev
Ye. Kanzharkan
A. Kidyrali
S. Frolov
N. Bektenov
author_facet Ye. Tileuberdi
Ye. Imanbayev
Ye. Kanzharkan
A. Kidyrali
S. Frolov
N. Bektenov
author_sort Ye. Tileuberdi
collection DOAJ
description In the paper, the physical and chemical characteristics of sulfur cake from Stepnogorsk Sulfuric Acid Plant (SSAP LLP) were studied. During the production of sulfuric acid, 130–200 tons of sulfur-containing residues are accumulated per year, the storage of which negatively affects the environment. The peaks of IR spectrum analyses are linked to the stretching vibrations of S=O, S-S bonds, and O-S-O groups. The chemical composition of the filtration waste of molten sulfur from the settling tanks of the Stepnogorsk sulfuric acid plant is represented by the following elements: S (about 60 wt.%), O, Na, Mg, Al, Si, Cl, Ca, Fe, Cu, Pb, and Zn. The content of organic compounds in sulfur cake is low, and mineral components – gypsum, calcium sulfate, and silicates are contained in insignificant quantities, which makes it possible to use it for the production of composite materials for construction purposes. Using compositions will improve the properties of materials and provide an opportunity to sell additional volumes of sulfur on the domestic market, which will reduce the consequences of excess production and the environmental burden from long-term storage of sulfur-containing waste.
format Article
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institution Kabale University
issn 1562-3920
2522-4867
language English
publishDate 2024-12-01
publisher al-Farabi Kazakh National University
record_format Article
series Eurasian Chemico-Technological Journal
spelling doaj-art-073fd5f52ea9464d8804dfc206ef72ae2025-01-29T15:41:44Zengal-Farabi Kazakh National UniversityEurasian Chemico-Technological Journal1562-39202522-48672024-12-0126410.18321/ectj1650Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid PlantYe. Tileuberdi0Ye. Imanbayev1Ye. Kanzharkan2A. Kidyrali3S. Frolov4N. Bektenov5Institute of Combustion Problems, 172, Bogenbai batyr str., 050012, Almaty, Kazakhstan; Abai Kazakh National Pedagogical University, 13, Dostyk ave., 050010, Almaty, KazakhstanInstitute of Combustion Problems, 172, Bogenbai batyr str., 050012, Almaty, KazakhstanInstitute of Combustion Problems, 172, Bogenbai batyr str., 050012, Almaty, Kazakhstan; Abai Kazakh National Pedagogical University, 13, Dostyk ave., 050010, Almaty, KazakhstanInstitute of Combustion Problems, 172, Bogenbai batyr str., 050012, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 71, al-Farabi ave., 050040, Almaty, KazakhstanStepnogorsk sulfuric acid plant, Industrial Zone 6, complex No. 5, Stepnogorsk, KazakhstanAbai Kazakh National Pedagogical University, 13, Dostyk ave., 050010, Almaty, Kazakhstan In the paper, the physical and chemical characteristics of sulfur cake from Stepnogorsk Sulfuric Acid Plant (SSAP LLP) were studied. During the production of sulfuric acid, 130–200 tons of sulfur-containing residues are accumulated per year, the storage of which negatively affects the environment. The peaks of IR spectrum analyses are linked to the stretching vibrations of S=O, S-S bonds, and O-S-O groups. The chemical composition of the filtration waste of molten sulfur from the settling tanks of the Stepnogorsk sulfuric acid plant is represented by the following elements: S (about 60 wt.%), O, Na, Mg, Al, Si, Cl, Ca, Fe, Cu, Pb, and Zn. The content of organic compounds in sulfur cake is low, and mineral components – gypsum, calcium sulfate, and silicates are contained in insignificant quantities, which makes it possible to use it for the production of composite materials for construction purposes. Using compositions will improve the properties of materials and provide an opportunity to sell additional volumes of sulfur on the domestic market, which will reduce the consequences of excess production and the environmental burden from long-term storage of sulfur-containing waste. https://ect-journal.kz/index.php/ectj/article/view/1661Sulfur Sulfur cake Sulfuric Acid Plant Modification Sulfur-containing waste
spellingShingle Ye. Tileuberdi
Ye. Imanbayev
Ye. Kanzharkan
A. Kidyrali
S. Frolov
N. Bektenov
Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
Eurasian Chemico-Technological Journal
Sulfur
Sulfur cake
Sulfuric Acid Plant
Modification
Sulfur-containing waste
title Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
title_full Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
title_fullStr Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
title_full_unstemmed Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
title_short Identification and Characterization of Sulfur Cake from Stepnogorsk Sulfuric Acid Plant
title_sort identification and characterization of sulfur cake from stepnogorsk sulfuric acid plant
topic Sulfur
Sulfur cake
Sulfuric Acid Plant
Modification
Sulfur-containing waste
url https://ect-journal.kz/index.php/ectj/article/view/1661
work_keys_str_mv AT yetileuberdi identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant
AT yeimanbayev identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant
AT yekanzharkan identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant
AT akidyrali identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant
AT sfrolov identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant
AT nbektenov identificationandcharacterizationofsulfurcakefromstepnogorsksulfuricacidplant