Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation

Indonesia is an agricultural country with the potential to grow many plants as natural fiber sources. In order to improve its properties, natural fiber needs to be treated by applying nanomaterial so that it can compete with the characteristics of synthetic fibers. The study aims to determine the in...

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Main Authors: Rahmad Ikrom Ramadhan, Heru Suryanto, Ahmad Atif Fikri, Aminnudin Aminnudin, Jibril Maulana, Faqih Fadillah, Mohamed T Mito, Kemal Masera
Format: Article
Language:English
Published: Universitas Negeri Malang 2024-05-01
Series:Journal of Mechanical Engineering Science and Technology
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Online Access:https://journal2.um.ac.id/index.php/jmest/article/view/43755
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author Rahmad Ikrom Ramadhan
Heru Suryanto
Ahmad Atif Fikri
Aminnudin Aminnudin
Jibril Maulana
Faqih Fadillah
Mohamed T Mito
Kemal Masera
author_facet Rahmad Ikrom Ramadhan
Heru Suryanto
Ahmad Atif Fikri
Aminnudin Aminnudin
Jibril Maulana
Faqih Fadillah
Mohamed T Mito
Kemal Masera
author_sort Rahmad Ikrom Ramadhan
collection DOAJ
description Indonesia is an agricultural country with the potential to grow many plants as natural fiber sources. In order to improve its properties, natural fiber needs to be treated by applying nanomaterial so that it can compete with the characteristics of synthetic fibers. The study aims to determine the influence of adding titanium dioxide (TiO2) nanoparticles on pineapple leaf fiber (PALF) characteristics. The PALF was collected from the Subang plantation (Indonesia). The chemical treatment was carried out with pre-treatment using an alkalization process for 3 hours, and the oxidation process was carried out with TEMPO. TiO2 nanoparticle grafting was carried out by adding a silane solution with a ratio of 1:10 with alcohol. The characteristics of PALF were observed using XRD, FTIR, SEM, and tensile tests. The results show that the crystallinity of the PALF increased after TEMPO treatment. PALF form Si-O-C bond identified at a wavelength of 1158 cm-1 after silane treatment. Ti – O – Si functional groups were identified in the 660 cm-1 – 670 cm-1 wavelength range. In the fiber surface, agglomerated TiO2 nanoparticles are formed and increase with increasing TiO2 nanoparticle concentration. The tensile stress of treated PALF is increased by 125%, with the highest tensile strength of 1279.18 MPa, obtained by TiO2 nanoparticle concentration of 1.0%.
format Article
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institution Kabale University
issn 2580-0817
2580-2402
language English
publishDate 2024-05-01
publisher Universitas Negeri Malang
record_format Article
series Journal of Mechanical Engineering Science and Technology
spelling doaj-art-06603c4fba8f428ba0b9e0ec380bc88a2025-02-04T00:25:57ZengUniversitas Negeri MalangJournal of Mechanical Engineering Science and Technology2580-08172580-24022024-05-0181829110.17977/um0168i12024p08211358Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation OxidationRahmad Ikrom Ramadhan0Heru Suryanto1Ahmad Atif FikriAminnudin AminnudinJibril MaulanaFaqih FadillahMohamed T Mito2Kemal Masera3Universitas Negeri MalangUMArab Academy for Science, Technology and Maritime Transport, AlexandriaMechanical, Biomedical and Design Engineering, Aston UniversityIndonesia is an agricultural country with the potential to grow many plants as natural fiber sources. In order to improve its properties, natural fiber needs to be treated by applying nanomaterial so that it can compete with the characteristics of synthetic fibers. The study aims to determine the influence of adding titanium dioxide (TiO2) nanoparticles on pineapple leaf fiber (PALF) characteristics. The PALF was collected from the Subang plantation (Indonesia). The chemical treatment was carried out with pre-treatment using an alkalization process for 3 hours, and the oxidation process was carried out with TEMPO. TiO2 nanoparticle grafting was carried out by adding a silane solution with a ratio of 1:10 with alcohol. The characteristics of PALF were observed using XRD, FTIR, SEM, and tensile tests. The results show that the crystallinity of the PALF increased after TEMPO treatment. PALF form Si-O-C bond identified at a wavelength of 1158 cm-1 after silane treatment. Ti – O – Si functional groups were identified in the 660 cm-1 – 670 cm-1 wavelength range. In the fiber surface, agglomerated TiO2 nanoparticles are formed and increase with increasing TiO2 nanoparticle concentration. The tensile stress of treated PALF is increased by 125%, with the highest tensile strength of 1279.18 MPa, obtained by TiO2 nanoparticle concentration of 1.0%.https://journal2.um.ac.id/index.php/jmest/article/view/43755pineapple leaf fiber, tempo, tensile strength, titanium dioxide
spellingShingle Rahmad Ikrom Ramadhan
Heru Suryanto
Ahmad Atif Fikri
Aminnudin Aminnudin
Jibril Maulana
Faqih Fadillah
Mohamed T Mito
Kemal Masera
Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
Journal of Mechanical Engineering Science and Technology
pineapple leaf fiber, tempo, tensile strength, titanium dioxide
title Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
title_full Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
title_fullStr Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
title_full_unstemmed Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
title_short Effect of Addition Titanium Dioxide Nanoparticle on Properties of Pineapple Leaf Fiber Mediated TEMPO Oxidation Oxidation
title_sort effect of addition titanium dioxide nanoparticle on properties of pineapple leaf fiber mediated tempo oxidation oxidation
topic pineapple leaf fiber, tempo, tensile strength, titanium dioxide
url https://journal2.um.ac.id/index.php/jmest/article/view/43755
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