Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group

Two novel poly(aryl ether)s containing β-naphthalene pendant group were synthesized and the structures of these polymers were confirmed by 1HNMR spectroscopy. The polymers exhibited good thermal stabilities with high Tg of 256°C and 274°C, respectively. The polymers are soluble in common organic sol...

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Main Authors: L. Wang, D. Tao, X. Z. Xiang, G. M. Zhu
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2014/353540
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author L. Wang
D. Tao
X. Z. Xiang
G. M. Zhu
author_facet L. Wang
D. Tao
X. Z. Xiang
G. M. Zhu
author_sort L. Wang
collection DOAJ
description Two novel poly(aryl ether)s containing β-naphthalene pendant group were synthesized and the structures of these polymers were confirmed by 1HNMR spectroscopy. The polymers exhibited good thermal stabilities with high Tg of 256°C and 274°C, respectively. The polymers are soluble in common organic solvents, such as DMAc, DMSO, CH2Cl2, and CHCl3, and can be electrospun into microfiber (1–5 µm) with lots of nanopores (<100 nm) from CHCl3 solution. These fibers showed high hydrophobicity, and the contact angle of fibers is above 120°.
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institution OA Journals
issn 2090-9063
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publishDate 2014-01-01
publisher Wiley
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series Journal of Chemistry
spelling doaj-art-0591692fb45f453b8b68098175f910922025-08-20T02:02:58ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/353540353540Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant GroupL. Wang0D. Tao1X. Z. Xiang2G. M. Zhu3Shenzhen Key Laboratory of Special Functional Materials and College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, ChinaShenzhen Key Laboratory of Special Functional Materials and College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, ChinaShenzhen Key Laboratory of Special Functional Materials and College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, ChinaShenzhen Key Laboratory of Special Functional Materials and College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, ChinaTwo novel poly(aryl ether)s containing β-naphthalene pendant group were synthesized and the structures of these polymers were confirmed by 1HNMR spectroscopy. The polymers exhibited good thermal stabilities with high Tg of 256°C and 274°C, respectively. The polymers are soluble in common organic solvents, such as DMAc, DMSO, CH2Cl2, and CHCl3, and can be electrospun into microfiber (1–5 µm) with lots of nanopores (<100 nm) from CHCl3 solution. These fibers showed high hydrophobicity, and the contact angle of fibers is above 120°.http://dx.doi.org/10.1155/2014/353540
spellingShingle L. Wang
D. Tao
X. Z. Xiang
G. M. Zhu
Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
Journal of Chemistry
title Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
title_full Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
title_fullStr Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
title_full_unstemmed Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
title_short Synthesis and Preliminary Properties of Novel Poly(aryl ether)s Containing β-Naphthalene Pendant Group
title_sort synthesis and preliminary properties of novel poly aryl ether s containing β naphthalene pendant group
url http://dx.doi.org/10.1155/2014/353540
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AT xzxiang synthesisandpreliminarypropertiesofnovelpolyaryletherscontainingbnaphthalenependantgroup
AT gmzhu synthesisandpreliminarypropertiesofnovelpolyaryletherscontainingbnaphthalenependantgroup