Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode

Parathion has been determined with voltammetric technique based on a novel sensor fabricated by electropolymerization of safranine on a glassy carbon electrode (GCE). The electrochemical behavior of poly(safranine) film electrode and its electrocatalytic activity toward parathion were studied in det...

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Main Author: Xingyuan Liu
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.4061/2011/986494
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author Xingyuan Liu
author_facet Xingyuan Liu
author_sort Xingyuan Liu
collection DOAJ
description Parathion has been determined with voltammetric technique based on a novel sensor fabricated by electropolymerization of safranine on a glassy carbon electrode (GCE). The electrochemical behavior of poly(safranine) film electrode and its electrocatalytic activity toward parathion were studied in detail by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). All experimental parameters were optimized, and LSV was proposed for its determination. In optimal working conditions, the reduction current of parathion at this poly(safranine)-modified electrode exhibited a good linear relationship with parathion concentration in the range of 3.43×10−8 to 3.43×10−5 mol L−1. The detection limit was 1.0×10−8 mol L−1. The high sensitivity and selectivity of the sensor were demonstrated by its practical application for the determination of trace amounts of parathion in fruit samples.
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series International Journal of Electrochemistry
spelling doaj-art-05608e36172542619d5a10df1dec924d2025-02-03T06:05:23ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/986494986494Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film ElectrodeXingyuan Liu0Department of Chemistry, Teachers' College of Simao, Puer, Yunnan 665000, ChinaParathion has been determined with voltammetric technique based on a novel sensor fabricated by electropolymerization of safranine on a glassy carbon electrode (GCE). The electrochemical behavior of poly(safranine) film electrode and its electrocatalytic activity toward parathion were studied in detail by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). All experimental parameters were optimized, and LSV was proposed for its determination. In optimal working conditions, the reduction current of parathion at this poly(safranine)-modified electrode exhibited a good linear relationship with parathion concentration in the range of 3.43×10−8 to 3.43×10−5 mol L−1. The detection limit was 1.0×10−8 mol L−1. The high sensitivity and selectivity of the sensor were demonstrated by its practical application for the determination of trace amounts of parathion in fruit samples.http://dx.doi.org/10.4061/2011/986494
spellingShingle Xingyuan Liu
Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
International Journal of Electrochemistry
title Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
title_full Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
title_fullStr Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
title_full_unstemmed Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
title_short Electrochemical Sensor for Determination of Parathion Based on Electropolymerization Poly(Safranine) Film Electrode
title_sort electrochemical sensor for determination of parathion based on electropolymerization poly safranine film electrode
url http://dx.doi.org/10.4061/2011/986494
work_keys_str_mv AT xingyuanliu electrochemicalsensorfordeterminationofparathionbasedonelectropolymerizationpolysafraninefilmelectrode