Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment

A high-entropy AlCrFeNiMn alloy (AM-HEA) was corroded in a high-temperature supercritical CO2 environment at 500 °C and 25 MPa. The AM-HEA has a duplex structure with Ni,Al-enriched α region domains surrounded by Fe,Cr-enriched B2 region domains. The B2 region experienced severe corrosion, leading t...

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Main Authors: Wanhuan Yang, Xueli Zhao, Jichun Zou, Mengyao Chen, Qi Liu, Wen Yang, Shen Li, Pengrui Qiao, Weihua Zhong
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Materials & Design
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Online Access:http://www.sciencedirect.com/science/article/pii/S0264127525000425
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author Wanhuan Yang
Xueli Zhao
Jichun Zou
Mengyao Chen
Qi Liu
Wen Yang
Shen Li
Pengrui Qiao
Weihua Zhong
author_facet Wanhuan Yang
Xueli Zhao
Jichun Zou
Mengyao Chen
Qi Liu
Wen Yang
Shen Li
Pengrui Qiao
Weihua Zhong
author_sort Wanhuan Yang
collection DOAJ
description A high-entropy AlCrFeNiMn alloy (AM-HEA) was corroded in a high-temperature supercritical CO2 environment at 500 °C and 25 MPa. The AM-HEA has a duplex structure with Ni,Al-enriched α region domains surrounded by Fe,Cr-enriched B2 region domains. The B2 region experienced severe corrosion, leading to the formation of large-faceted Mn-rich oxides on the exterior and flocculent oxides in the interior. Conversely, the Ni,Mn-rich domains showed minimal corrosion. A uniform, thin Al2O3 layer developed as a subsurface layer on both structures, enhancing the corrosion resistance of the AM-HEA.
format Article
id doaj-art-04dd6633710c408c86d71c1856fbbfc3
institution Kabale University
issn 0264-1275
language English
publishDate 2025-02-01
publisher Elsevier
record_format Article
series Materials & Design
spelling doaj-art-04dd6633710c408c86d71c1856fbbfc32025-01-19T06:24:08ZengElsevierMaterials & Design0264-12752025-02-01250113622Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environmentWanhuan Yang0Xueli Zhao1Jichun Zou2Mengyao Chen3Qi Liu4Wen Yang5Shen Li6Pengrui Qiao7Weihua Zhong8China Institute of Atomic Energy, Beijing 102413, ChinaChina Institute of Atomic Energy, Beijing 102413, ChinaChina Institute of Atomic Energy, Beijing 102413, China; School of Advanced Manufacturing, Nanchang University, Nanchang 330031, ChinaChina Institute of Atomic Energy, Beijing 102413, ChinaCollege of Materials Science and Engineering, Hunan University, Changsha, Hunan 413000, ChinaChina Institute of Atomic Energy, Beijing 102413, ChinaSchool of Advanced Manufacturing, Nanchang University, Nanchang 330031, China; Corresponding authors.China Institute of Atomic Energy, Beijing 102413, China; Corresponding authors.China Institute of Atomic Energy, Beijing 102413, ChinaA high-entropy AlCrFeNiMn alloy (AM-HEA) was corroded in a high-temperature supercritical CO2 environment at 500 °C and 25 MPa. The AM-HEA has a duplex structure with Ni,Al-enriched α region domains surrounded by Fe,Cr-enriched B2 region domains. The B2 region experienced severe corrosion, leading to the formation of large-faceted Mn-rich oxides on the exterior and flocculent oxides in the interior. Conversely, the Ni,Mn-rich domains showed minimal corrosion. A uniform, thin Al2O3 layer developed as a subsurface layer on both structures, enhancing the corrosion resistance of the AM-HEA.http://www.sciencedirect.com/science/article/pii/S0264127525000425High-Entropy AlloySupercritical CO2Duplex StructureCorrosion ResistanceCarburization
spellingShingle Wanhuan Yang
Xueli Zhao
Jichun Zou
Mengyao Chen
Qi Liu
Wen Yang
Shen Li
Pengrui Qiao
Weihua Zhong
Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
Materials & Design
High-Entropy Alloy
Supercritical CO2
Duplex Structure
Corrosion Resistance
Carburization
title Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
title_full Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
title_fullStr Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
title_full_unstemmed Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
title_short Corrosion behavior of a high-entropy AlCrFeNiMn alloy in a high-temperature supercritical CO2 environment
title_sort corrosion behavior of a high entropy alcrfenimn alloy in a high temperature supercritical co2 environment
topic High-Entropy Alloy
Supercritical CO2
Duplex Structure
Corrosion Resistance
Carburization
url http://www.sciencedirect.com/science/article/pii/S0264127525000425
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