Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes
New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value 0.398×10-6 S cm−1 has been achieved. XRD and FT-IR studies have...
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.1155/2015/494308 |
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| author | Chithra M. Mathew K. Kesavan S. Rajendran |
| author_facet | Chithra M. Mathew K. Kesavan S. Rajendran |
| author_sort | Chithra M. Mathew |
| collection | DOAJ |
| description | New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value 0.398×10-6 S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C. |
| format | Article |
| id | doaj-art-04a5c85d978d4141841af057b708118f |
| institution | Kabale University |
| issn | 2090-3529 2090-3537 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-04a5c85d978d4141841af057b708118f2025-02-03T06:13:24ZengWileyInternational Journal of Electrochemistry2090-35292090-35372015-01-01201510.1155/2015/494308494308Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte MembranesChithra M. Mathew0K. Kesavan1S. Rajendran2Department of Physics, Alagappa University, Karaikudi, Tamil Nadu 630 004, IndiaDepartment of Physics, Alagappa University, Karaikudi, Tamil Nadu 630 004, IndiaDepartment of Physics, Alagappa University, Karaikudi, Tamil Nadu 630 004, IndiaNew gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value 0.398×10-6 S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.http://dx.doi.org/10.1155/2015/494308 |
| spellingShingle | Chithra M. Mathew K. Kesavan S. Rajendran Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes International Journal of Electrochemistry |
| title | Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes |
| title_full | Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes |
| title_fullStr | Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes |
| title_full_unstemmed | Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes |
| title_short | Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes |
| title_sort | structural and electrochemical analysis of pmma based gel electrolyte membranes |
| url | http://dx.doi.org/10.1155/2015/494308 |
| work_keys_str_mv | AT chithrammathew structuralandelectrochemicalanalysisofpmmabasedgelelectrolytemembranes AT kkesavan structuralandelectrochemicalanalysisofpmmabasedgelelectrolytemembranes AT srajendran structuralandelectrochemicalanalysisofpmmabasedgelelectrolytemembranes |